(3aR*,5R*)-5-(4-Chloro­phen­yl)-1,2,3,3a-tetra­hydro­benzo[e]pyrrolo­[2,1-b][1,3]ox­azepin-10(5H)-one

The title compound, C(18)H(16)ClNO(2), is the main product of a photoreaction. The two benzene rings make a dihedral angle of 86.40 (2)° with each other. The 1,3-oxazepine C atom to which the 4-chloro­phenyl group is attached and the C atom of the 4-chloro­phenyl group attached to the 1,3-oxazepine...

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Detalles Bibliográficos
Autores principales: Jin, Yun-Zhou, Zhang, Rong-Hua, Fu, Da-Xu, Lv, Yao-Kang
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2011
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3152057/
https://www.ncbi.nlm.nih.gov/pubmed/21837002
http://dx.doi.org/10.1107/S1600536811020265
Descripción
Sumario:The title compound, C(18)H(16)ClNO(2), is the main product of a photoreaction. The two benzene rings make a dihedral angle of 86.40 (2)° with each other. The 1,3-oxazepine C atom to which the 4-chloro­phenyl group is attached and the C atom of the 4-chloro­phenyl group attached to the 1,3-oxazepine ring are chiral C atoms, but the crystal is a racemate in which the enanti­omers are linked by a pair of weak inter­molecular C—H⋯O hydrogen bond, forming an inversion dimer.

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