(3aR*,5R*)-5-(4-Chloro­phen­yl)-1,2,3,3a-tetra­hydro­benzo[e]pyrrolo­[2,1-b][1,3]ox­azepin-10(5H)-one

The title compound, C(18)H(16)ClNO(2), is the main product of a photoreaction. The two benzene rings make a dihedral angle of 86.40 (2)° with each other. The 1,3-oxazepine C atom to which the 4-chloro­phenyl group is attached and the C atom of the 4-chloro­phenyl group attached to the 1,3-oxazepine...

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Detalles Bibliográficos
Autores principales: Jin, Yun-Zhou, Zhang, Rong-Hua, Fu, Da-Xu, Lv, Yao-Kang
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2011
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3152057/
https://www.ncbi.nlm.nih.gov/pubmed/21837002
http://dx.doi.org/10.1107/S1600536811020265
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author Jin, Yun-Zhou
Zhang, Rong-Hua
Fu, Da-Xu
Lv, Yao-Kang
author_facet Jin, Yun-Zhou
Zhang, Rong-Hua
Fu, Da-Xu
Lv, Yao-Kang
author_sort Jin, Yun-Zhou
collection PubMed
description The title compound, C(18)H(16)ClNO(2), is the main product of a photoreaction. The two benzene rings make a dihedral angle of 86.40 (2)° with each other. The 1,3-oxazepine C atom to which the 4-chloro­phenyl group is attached and the C atom of the 4-chloro­phenyl group attached to the 1,3-oxazepine ring are chiral C atoms, but the crystal is a racemate in which the enanti­omers are linked by a pair of weak inter­molecular C—H⋯O hydrogen bond, forming an inversion dimer.
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spelling pubmed-31520572011-08-11 (3aR*,5R*)-5-(4-Chloro­phen­yl)-1,2,3,3a-tetra­hydro­benzo[e]pyrrolo­[2,1-b][1,3]ox­azepin-10(5H)-one Jin, Yun-Zhou Zhang, Rong-Hua Fu, Da-Xu Lv, Yao-Kang Acta Crystallogr Sect E Struct Rep Online Organic Papers The title compound, C(18)H(16)ClNO(2), is the main product of a photoreaction. The two benzene rings make a dihedral angle of 86.40 (2)° with each other. The 1,3-oxazepine C atom to which the 4-chloro­phenyl group is attached and the C atom of the 4-chloro­phenyl group attached to the 1,3-oxazepine ring are chiral C atoms, but the crystal is a racemate in which the enanti­omers are linked by a pair of weak inter­molecular C—H⋯O hydrogen bond, forming an inversion dimer. International Union of Crystallography 2011-06-11 /pmc/articles/PMC3152057/ /pubmed/21837002 http://dx.doi.org/10.1107/S1600536811020265 Text en © Jin et al. 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Jin, Yun-Zhou
Zhang, Rong-Hua
Fu, Da-Xu
Lv, Yao-Kang
(3aR*,5R*)-5-(4-Chloro­phen­yl)-1,2,3,3a-tetra­hydro­benzo[e]pyrrolo­[2,1-b][1,3]ox­azepin-10(5H)-one
title (3aR*,5R*)-5-(4-Chloro­phen­yl)-1,2,3,3a-tetra­hydro­benzo[e]pyrrolo­[2,1-b][1,3]ox­azepin-10(5H)-one
title_full (3aR*,5R*)-5-(4-Chloro­phen­yl)-1,2,3,3a-tetra­hydro­benzo[e]pyrrolo­[2,1-b][1,3]ox­azepin-10(5H)-one
title_fullStr (3aR*,5R*)-5-(4-Chloro­phen­yl)-1,2,3,3a-tetra­hydro­benzo[e]pyrrolo­[2,1-b][1,3]ox­azepin-10(5H)-one
title_full_unstemmed (3aR*,5R*)-5-(4-Chloro­phen­yl)-1,2,3,3a-tetra­hydro­benzo[e]pyrrolo­[2,1-b][1,3]ox­azepin-10(5H)-one
title_short (3aR*,5R*)-5-(4-Chloro­phen­yl)-1,2,3,3a-tetra­hydro­benzo[e]pyrrolo­[2,1-b][1,3]ox­azepin-10(5H)-one
title_sort (3ar*,5r*)-5-(4-chloro­phen­yl)-1,2,3,3a-tetra­hydro­benzo[e]pyrrolo­[2,1-b][1,3]ox­azepin-10(5h)-one
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3152057/
https://www.ncbi.nlm.nih.gov/pubmed/21837002
http://dx.doi.org/10.1107/S1600536811020265
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