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catena-Poly[[[aqua(di-2-pyridylamine-κ(2) N (2),N (2′))manganese(II)]-μ-5-ferrocenylbenzene-1,3-dicarboxylato-κ(3) O (1),O (1′):O (3)] methanol monosolvate monohydrate]
In the title coordination polymer, {[FeMn(C(5)H(5))(C(13)H(7)O(4))(C(10)H(9)N(3))(H(2)O)]·CH(3)OH·H(2)O}(n), the Mn(II) ion has a distorted octahedral coordination geometry and is ligated by two N atoms from two di-2-pyridylamine molecules, three O atoms from two 5-ferrocenylbenzene-1,3-dicarbox...
Autores principales: | , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2011
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3152059/ https://www.ncbi.nlm.nih.gov/pubmed/21836962 http://dx.doi.org/10.1107/S1600536811022781 |
Sumario: | In the title coordination polymer, {[FeMn(C(5)H(5))(C(13)H(7)O(4))(C(10)H(9)N(3))(H(2)O)]·CH(3)OH·H(2)O}(n), the Mn(II) ion has a distorted octahedral coordination geometry and is ligated by two N atoms from two di-2-pyridylamine molecules, three O atoms from two 5-ferrocenylbenzene-1,3-dicarboxylate anions and one O atom from a coordinated water molecule. The Mn—O distances range from 2.151 (2) to 2.5093 (19) Å, while the Mn—N distances are 2.226 (2) and 2.248 (2) Å. Each 5-ferrocenylbenzene-1,5-dicarboxylate anion links to two Mn(II) ions, resulting in a chain along the b axis. A three-dimensional network of N—H⋯O and O—H⋯O hydrogen bonds helps to stabilize the crystal packing. |
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