catena-Poly[[[aqua­(di-2-pyridyl­amine-κ(2) N (2),N (2′))manganese(II)]-μ-5-ferrocenyl­benzene-1,3-dicarboxyl­ato-κ(3) O (1),O (1′):O (3)] methanol monosolvate monohydrate]

In the title coordination polymer, {[FeMn(C(5)H(5))(C(13)H(7)O(4))(C(10)H(9)N(3))(H(2)O)]·CH(3)OH·H(2)O}(n), the Mn(II) ion has a distorted octa­hedral coordination geometry and is ligated by two N atoms from two di-2-pyridyl­amine mol­ecules, three O atoms from two 5-ferrocenyl­benzene-1,3-dicarbox...

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Detalles Bibliográficos
Autores principales: Liu, Wei, Zhang, Gang
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2011
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3152059/
https://www.ncbi.nlm.nih.gov/pubmed/21836962
http://dx.doi.org/10.1107/S1600536811022781
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author Liu, Wei
Zhang, Gang
author_facet Liu, Wei
Zhang, Gang
author_sort Liu, Wei
collection PubMed
description In the title coordination polymer, {[FeMn(C(5)H(5))(C(13)H(7)O(4))(C(10)H(9)N(3))(H(2)O)]·CH(3)OH·H(2)O}(n), the Mn(II) ion has a distorted octa­hedral coordination geometry and is ligated by two N atoms from two di-2-pyridyl­amine mol­ecules, three O atoms from two 5-ferrocenyl­benzene-1,3-dicarboxyl­ate anions and one O atom from a coordinated water mol­ecule. The Mn—O distances range from 2.151 (2) to 2.5093 (19) Å, while the Mn—N distances are 2.226 (2) and 2.248 (2) Å. Each 5-ferrocenyl­benzene-1,5-dicarboxyl­ate anion links to two Mn(II) ions, resulting in a chain along the b axis. A three-dimensional network of N—H⋯O and O—H⋯O hydrogen bonds helps to stabilize the crystal packing.
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spelling pubmed-31520592011-08-11 catena-Poly[[[aqua­(di-2-pyridyl­amine-κ(2) N (2),N (2′))manganese(II)]-μ-5-ferrocenyl­benzene-1,3-dicarboxyl­ato-κ(3) O (1),O (1′):O (3)] methanol monosolvate monohydrate] Liu, Wei Zhang, Gang Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title coordination polymer, {[FeMn(C(5)H(5))(C(13)H(7)O(4))(C(10)H(9)N(3))(H(2)O)]·CH(3)OH·H(2)O}(n), the Mn(II) ion has a distorted octa­hedral coordination geometry and is ligated by two N atoms from two di-2-pyridyl­amine mol­ecules, three O atoms from two 5-ferrocenyl­benzene-1,3-dicarboxyl­ate anions and one O atom from a coordinated water mol­ecule. The Mn—O distances range from 2.151 (2) to 2.5093 (19) Å, while the Mn—N distances are 2.226 (2) and 2.248 (2) Å. Each 5-ferrocenyl­benzene-1,5-dicarboxyl­ate anion links to two Mn(II) ions, resulting in a chain along the b axis. A three-dimensional network of N—H⋯O and O—H⋯O hydrogen bonds helps to stabilize the crystal packing. International Union of Crystallography 2011-06-25 /pmc/articles/PMC3152059/ /pubmed/21836962 http://dx.doi.org/10.1107/S1600536811022781 Text en © Liu and Zhang 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Liu, Wei
Zhang, Gang
catena-Poly[[[aqua­(di-2-pyridyl­amine-κ(2) N (2),N (2′))manganese(II)]-μ-5-ferrocenyl­benzene-1,3-dicarboxyl­ato-κ(3) O (1),O (1′):O (3)] methanol monosolvate monohydrate]
title catena-Poly[[[aqua­(di-2-pyridyl­amine-κ(2) N (2),N (2′))manganese(II)]-μ-5-ferrocenyl­benzene-1,3-dicarboxyl­ato-κ(3) O (1),O (1′):O (3)] methanol monosolvate monohydrate]
title_full catena-Poly[[[aqua­(di-2-pyridyl­amine-κ(2) N (2),N (2′))manganese(II)]-μ-5-ferrocenyl­benzene-1,3-dicarboxyl­ato-κ(3) O (1),O (1′):O (3)] methanol monosolvate monohydrate]
title_fullStr catena-Poly[[[aqua­(di-2-pyridyl­amine-κ(2) N (2),N (2′))manganese(II)]-μ-5-ferrocenyl­benzene-1,3-dicarboxyl­ato-κ(3) O (1),O (1′):O (3)] methanol monosolvate monohydrate]
title_full_unstemmed catena-Poly[[[aqua­(di-2-pyridyl­amine-κ(2) N (2),N (2′))manganese(II)]-μ-5-ferrocenyl­benzene-1,3-dicarboxyl­ato-κ(3) O (1),O (1′):O (3)] methanol monosolvate monohydrate]
title_short catena-Poly[[[aqua­(di-2-pyridyl­amine-κ(2) N (2),N (2′))manganese(II)]-μ-5-ferrocenyl­benzene-1,3-dicarboxyl­ato-κ(3) O (1),O (1′):O (3)] methanol monosolvate monohydrate]
title_sort catena-poly[[[aqua­(di-2-pyridyl­amine-κ(2) n (2),n (2′))manganese(ii)]-μ-5-ferrocenyl­benzene-1,3-dicarboxyl­ato-κ(3) o (1),o (1′):o (3)] methanol monosolvate monohydrate]
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3152059/
https://www.ncbi.nlm.nih.gov/pubmed/21836962
http://dx.doi.org/10.1107/S1600536811022781
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AT zhanggang catenapolyaquadi2pyridylaminek2n2n2manganeseiim5ferrocenylbenzene13dicarboxylatok3o1o1o3methanolmonosolvatemonohydrate

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