1-(3-Fluoro­phen­yl)-4,4,6-trimethyl-3,4-dihydro­pyrimidine-2(1H)-thione

In the title compound, C(13)H(15)FN(2)S, the dihydro­pyrimidine ring is essentially planar, with a maximum deviation of 0.086 (3) Å from the mean plane of the rest of the ring for the dimethyl­ated C atom. The benzene ring is almost perpendicular to the dihydro­pyrimidine ring, with a dihedral angle...

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Detalles Bibliográficos
Autores principales: Yamin, Bohari M., Lawi, Ruhana L., Salem, Halima F.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2011
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3152063/
https://www.ncbi.nlm.nih.gov/pubmed/21837181
http://dx.doi.org/10.1107/S1600536811023671
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author Yamin, Bohari M.
Lawi, Ruhana L.
Salem, Halima F.
author_facet Yamin, Bohari M.
Lawi, Ruhana L.
Salem, Halima F.
author_sort Yamin, Bohari M.
collection PubMed
description In the title compound, C(13)H(15)FN(2)S, the dihydro­pyrimidine ring is essentially planar, with a maximum deviation of 0.086 (3) Å from the mean plane of the rest of the ring for the dimethyl­ated C atom. The benzene ring is almost perpendicular to the dihydro­pyrimidine ring, with a dihedral angle of 83.97 (14)°. The crystal packing is characterized by centrosymmetric dimers resulting from pairs of inter­molecular N—H⋯S hydrogen bonds. There are also C—H⋯π inter­actions.
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spelling pubmed-31520632011-08-11 1-(3-Fluoro­phen­yl)-4,4,6-trimethyl-3,4-dihydro­pyrimidine-2(1H)-thione Yamin, Bohari M. Lawi, Ruhana L. Salem, Halima F. Acta Crystallogr Sect E Struct Rep Online Organic Papers In the title compound, C(13)H(15)FN(2)S, the dihydro­pyrimidine ring is essentially planar, with a maximum deviation of 0.086 (3) Å from the mean plane of the rest of the ring for the dimethyl­ated C atom. The benzene ring is almost perpendicular to the dihydro­pyrimidine ring, with a dihedral angle of 83.97 (14)°. The crystal packing is characterized by centrosymmetric dimers resulting from pairs of inter­molecular N—H⋯S hydrogen bonds. There are also C—H⋯π inter­actions. International Union of Crystallography 2011-06-25 /pmc/articles/PMC3152063/ /pubmed/21837181 http://dx.doi.org/10.1107/S1600536811023671 Text en © Yamin et al. 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Yamin, Bohari M.
Lawi, Ruhana L.
Salem, Halima F.
1-(3-Fluoro­phen­yl)-4,4,6-trimethyl-3,4-dihydro­pyrimidine-2(1H)-thione
title 1-(3-Fluoro­phen­yl)-4,4,6-trimethyl-3,4-dihydro­pyrimidine-2(1H)-thione
title_full 1-(3-Fluoro­phen­yl)-4,4,6-trimethyl-3,4-dihydro­pyrimidine-2(1H)-thione
title_fullStr 1-(3-Fluoro­phen­yl)-4,4,6-trimethyl-3,4-dihydro­pyrimidine-2(1H)-thione
title_full_unstemmed 1-(3-Fluoro­phen­yl)-4,4,6-trimethyl-3,4-dihydro­pyrimidine-2(1H)-thione
title_short 1-(3-Fluoro­phen­yl)-4,4,6-trimethyl-3,4-dihydro­pyrimidine-2(1H)-thione
title_sort 1-(3-fluoro­phen­yl)-4,4,6-trimethyl-3,4-dihydro­pyrimidine-2(1h)-thione
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3152063/
https://www.ncbi.nlm.nih.gov/pubmed/21837181
http://dx.doi.org/10.1107/S1600536811023671
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