Bis(bicyclo­[2.2.1]hept-5-ene-2-carboxyl­ato)-1κ(2) O,O′;4κ(2) O,O′-di-μ(2)-chlorido-1:2κ(2) Cl;3:4κ(2) Cl-octa­methyl-1κ(2) C,2κ(2) C,3κ(2) C,4κ(2) C-di-μ(3)-oxido-1:2:3κ(3) O;2:3:4κ(3) O-tetra­tin(IV)

In the title compound, [Sn(4)(CH(3))(8)(C(8)H(9)O(2))(2)Cl(2)O(2)], the tetra­nuclear complex mol­ecule has crystallographically imposed inversion symmetry. The coordination polyhedron about the two central Sn atoms is distorted trigonal–bipyramidal, whilst the two peripheral metal atoms bonded to t...

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Detalles Bibliográficos
Autor principal: Ren, Yupo
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2011
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3152064/
https://www.ncbi.nlm.nih.gov/pubmed/21836958
http://dx.doi.org/10.1107/S1600536811023452
Descripción
Sumario:In the title compound, [Sn(4)(CH(3))(8)(C(8)H(9)O(2))(2)Cl(2)O(2)], the tetra­nuclear complex mol­ecule has crystallographically imposed inversion symmetry. The coordination polyhedron about the two central Sn atoms is distorted trigonal–bipyramidal, whilst the two peripheral metal atoms bonded to the carboxyl­ate groups have a distorted octa­hedral coordination geometry. In the crystal, mol­ecules are connected by long Sn⋯O contacts [3.139 (11) Å], forming chains along [011].

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