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Bis(bicyclo[2.2.1]hept-5-ene-2-carboxylato)-1κ(2) O,O′;4κ(2) O,O′-di-μ(2)-chlorido-1:2κ(2) Cl;3:4κ(2) Cl-octamethyl-1κ(2) C,2κ(2) C,3κ(2) C,4κ(2) C-di-μ(3)-oxido-1:2:3κ(3) O;2:3:4κ(3) O-tetratin(IV)
In the title compound, [Sn(4)(CH(3))(8)(C(8)H(9)O(2))(2)Cl(2)O(2)], the tetranuclear complex molecule has crystallographically imposed inversion symmetry. The coordination polyhedron about the two central Sn atoms is distorted trigonal–bipyramidal, whilst the two peripheral metal atoms bonded to t...
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
International Union of Crystallography
2011
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| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3152064/ https://www.ncbi.nlm.nih.gov/pubmed/21836958 http://dx.doi.org/10.1107/S1600536811023452 |
| _version_ | 1782209719126982656 |
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| author | Ren, Yupo |
| author_facet | Ren, Yupo |
| author_sort | Ren, Yupo |
| collection | PubMed |
| description | In the title compound, [Sn(4)(CH(3))(8)(C(8)H(9)O(2))(2)Cl(2)O(2)], the tetranuclear complex molecule has crystallographically imposed inversion symmetry. The coordination polyhedron about the two central Sn atoms is distorted trigonal–bipyramidal, whilst the two peripheral metal atoms bonded to the carboxylate groups have a distorted octahedral coordination geometry. In the crystal, molecules are connected by long Sn⋯O contacts [3.139 (11) Å], forming chains along [011]. |
| format | Online Article Text |
| id | pubmed-3152064 |
| institution | National Center for Biotechnology Information |
| language | English |
| publishDate | 2011 |
| publisher | International Union of Crystallography |
| record_format | MEDLINE/PubMed |
| spelling | pubmed-31520642011-08-11 Bis(bicyclo[2.2.1]hept-5-ene-2-carboxylato)-1κ(2) O,O′;4κ(2) O,O′-di-μ(2)-chlorido-1:2κ(2) Cl;3:4κ(2) Cl-octamethyl-1κ(2) C,2κ(2) C,3κ(2) C,4κ(2) C-di-μ(3)-oxido-1:2:3κ(3) O;2:3:4κ(3) O-tetratin(IV) Ren, Yupo Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title compound, [Sn(4)(CH(3))(8)(C(8)H(9)O(2))(2)Cl(2)O(2)], the tetranuclear complex molecule has crystallographically imposed inversion symmetry. The coordination polyhedron about the two central Sn atoms is distorted trigonal–bipyramidal, whilst the two peripheral metal atoms bonded to the carboxylate groups have a distorted octahedral coordination geometry. In the crystal, molecules are connected by long Sn⋯O contacts [3.139 (11) Å], forming chains along [011]. International Union of Crystallography 2011-06-25 /pmc/articles/PMC3152064/ /pubmed/21836958 http://dx.doi.org/10.1107/S1600536811023452 Text en © Yupo Ren 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
| spellingShingle | Metal-Organic Papers Ren, Yupo Bis(bicyclo[2.2.1]hept-5-ene-2-carboxylato)-1κ(2) O,O′;4κ(2) O,O′-di-μ(2)-chlorido-1:2κ(2) Cl;3:4κ(2) Cl-octamethyl-1κ(2) C,2κ(2) C,3κ(2) C,4κ(2) C-di-μ(3)-oxido-1:2:3κ(3) O;2:3:4κ(3) O-tetratin(IV) |
| title | Bis(bicyclo[2.2.1]hept-5-ene-2-carboxylato)-1κ(2)
O,O′;4κ(2)
O,O′-di-μ(2)-chlorido-1:2κ(2)
Cl;3:4κ(2)
Cl-octamethyl-1κ(2)
C,2κ(2)
C,3κ(2)
C,4κ(2)
C-di-μ(3)-oxido-1:2:3κ(3)
O;2:3:4κ(3)
O-tetratin(IV) |
| title_full | Bis(bicyclo[2.2.1]hept-5-ene-2-carboxylato)-1κ(2)
O,O′;4κ(2)
O,O′-di-μ(2)-chlorido-1:2κ(2)
Cl;3:4κ(2)
Cl-octamethyl-1κ(2)
C,2κ(2)
C,3κ(2)
C,4κ(2)
C-di-μ(3)-oxido-1:2:3κ(3)
O;2:3:4κ(3)
O-tetratin(IV) |
| title_fullStr | Bis(bicyclo[2.2.1]hept-5-ene-2-carboxylato)-1κ(2)
O,O′;4κ(2)
O,O′-di-μ(2)-chlorido-1:2κ(2)
Cl;3:4κ(2)
Cl-octamethyl-1κ(2)
C,2κ(2)
C,3κ(2)
C,4κ(2)
C-di-μ(3)-oxido-1:2:3κ(3)
O;2:3:4κ(3)
O-tetratin(IV) |
| title_full_unstemmed | Bis(bicyclo[2.2.1]hept-5-ene-2-carboxylato)-1κ(2)
O,O′;4κ(2)
O,O′-di-μ(2)-chlorido-1:2κ(2)
Cl;3:4κ(2)
Cl-octamethyl-1κ(2)
C,2κ(2)
C,3κ(2)
C,4κ(2)
C-di-μ(3)-oxido-1:2:3κ(3)
O;2:3:4κ(3)
O-tetratin(IV) |
| title_short | Bis(bicyclo[2.2.1]hept-5-ene-2-carboxylato)-1κ(2)
O,O′;4κ(2)
O,O′-di-μ(2)-chlorido-1:2κ(2)
Cl;3:4κ(2)
Cl-octamethyl-1κ(2)
C,2κ(2)
C,3κ(2)
C,4κ(2)
C-di-μ(3)-oxido-1:2:3κ(3)
O;2:3:4κ(3)
O-tetratin(IV) |
| title_sort | bis(bicyclo[2.2.1]hept-5-ene-2-carboxylato)-1κ(2)
o,o′;4κ(2)
o,o′-di-μ(2)-chlorido-1:2κ(2)
cl;3:4κ(2)
cl-octamethyl-1κ(2)
c,2κ(2)
c,3κ(2)
c,4κ(2)
c-di-μ(3)-oxido-1:2:3κ(3)
o;2:3:4κ(3)
o-tetratin(iv) |
| topic | Metal-Organic Papers |
| url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3152064/ https://www.ncbi.nlm.nih.gov/pubmed/21836958 http://dx.doi.org/10.1107/S1600536811023452 |
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