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Tetraethylammonium 4-hydroxybenzoate monohydrate
In the title compound, C(8)H(20)N(+)·C(7)H(5)O(3) (−)·H(2)O, the carboxylate group is slightly out of the plane of the parent benzene ring, the C—C—C—O torsion angles being 2.3 (2) and 2.0 (2)°. The carboxylate group and the hydroxy group form O—H⋯O hydrogen bonds, generating a head-to-tail chain...
Autores principales: | , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2011
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3152065/ https://www.ncbi.nlm.nih.gov/pubmed/21837161 http://dx.doi.org/10.1107/S1600536811024044 |
Sumario: | In the title compound, C(8)H(20)N(+)·C(7)H(5)O(3) (−)·H(2)O, the carboxylate group is slightly out of the plane of the parent benzene ring, the C—C—C—O torsion angles being 2.3 (2) and 2.0 (2)°. The carboxylate group and the hydroxy group form O—H⋯O hydrogen bonds, generating a head-to-tail chain along the b axis. Neighbouring hydrogen-bonded chains are linked by the water molecule, generating two independent O—H⋯O donor hydrogen bonds. The carboxylate group thus constructs a hydrogen-bonded host layer parallel to (10[Image: see text]). The tetraethylammonium cation is contained between these layers, forming a sandwich-like structure with an approximate interlayer distance of 10.03 Å. |
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