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Tetra­ethyl­ammonium 4-hy­droxy­benzoate monohydrate

In the title compound, C(8)H(20)N(+)·C(7)H(5)O(3) (−)·H(2)O, the carboxyl­ate group is slightly out of the plane of the parent benzene ring, the C—C—C—O torsion angles being 2.3 (2) and 2.0 (2)°. The carboxyl­ate group and the hy­droxy group form O—H⋯O hydrogen bonds, generating a head-to-tail chain...

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Detalles Bibliográficos
Autores principales: Li, Heping, Liu, Pei, Yang, Yunxia
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2011
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3152065/
https://www.ncbi.nlm.nih.gov/pubmed/21837161
http://dx.doi.org/10.1107/S1600536811024044
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author Li, Heping
Liu, Pei
Yang, Yunxia
author_facet Li, Heping
Liu, Pei
Yang, Yunxia
author_sort Li, Heping
collection PubMed
description In the title compound, C(8)H(20)N(+)·C(7)H(5)O(3) (−)·H(2)O, the carboxyl­ate group is slightly out of the plane of the parent benzene ring, the C—C—C—O torsion angles being 2.3 (2) and 2.0 (2)°. The carboxyl­ate group and the hy­droxy group form O—H⋯O hydrogen bonds, generating a head-to-tail chain along the b axis. Neighbouring hydrogen-bonded chains are linked by the water mol­ecule, generating two independent O—H⋯O donor hydrogen bonds. The carboxyl­ate group thus constructs a hydrogen-bonded host layer parallel to (10[Image: see text]). The tetra­ethyl­ammonium cation is contained between these layers, forming a sandwich-like structure with an approximate inter­layer distance of 10.03 Å.
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spelling pubmed-31520652011-08-11 Tetra­ethyl­ammonium 4-hy­droxy­benzoate monohydrate Li, Heping Liu, Pei Yang, Yunxia Acta Crystallogr Sect E Struct Rep Online Organic Papers In the title compound, C(8)H(20)N(+)·C(7)H(5)O(3) (−)·H(2)O, the carboxyl­ate group is slightly out of the plane of the parent benzene ring, the C—C—C—O torsion angles being 2.3 (2) and 2.0 (2)°. The carboxyl­ate group and the hy­droxy group form O—H⋯O hydrogen bonds, generating a head-to-tail chain along the b axis. Neighbouring hydrogen-bonded chains are linked by the water mol­ecule, generating two independent O—H⋯O donor hydrogen bonds. The carboxyl­ate group thus constructs a hydrogen-bonded host layer parallel to (10[Image: see text]). The tetra­ethyl­ammonium cation is contained between these layers, forming a sandwich-like structure with an approximate inter­layer distance of 10.03 Å. International Union of Crystallography 2011-06-25 /pmc/articles/PMC3152065/ /pubmed/21837161 http://dx.doi.org/10.1107/S1600536811024044 Text en © Li et al. 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Li, Heping
Liu, Pei
Yang, Yunxia
Tetra­ethyl­ammonium 4-hy­droxy­benzoate monohydrate
title Tetra­ethyl­ammonium 4-hy­droxy­benzoate monohydrate
title_full Tetra­ethyl­ammonium 4-hy­droxy­benzoate monohydrate
title_fullStr Tetra­ethyl­ammonium 4-hy­droxy­benzoate monohydrate
title_full_unstemmed Tetra­ethyl­ammonium 4-hy­droxy­benzoate monohydrate
title_short Tetra­ethyl­ammonium 4-hy­droxy­benzoate monohydrate
title_sort tetra­ethyl­ammonium 4-hy­droxy­benzoate monohydrate
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3152065/
https://www.ncbi.nlm.nih.gov/pubmed/21837161
http://dx.doi.org/10.1107/S1600536811024044
work_keys_str_mv AT liheping tetraethylammonium4hydroxybenzoatemonohydrate
AT liupei tetraethylammonium4hydroxybenzoatemonohydrate
AT yangyunxia tetraethylammonium4hydroxybenzoatemonohydrate