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Tetraethylammonium 4-hydroxybenzoate monohydrate
In the title compound, C(8)H(20)N(+)·C(7)H(5)O(3) (−)·H(2)O, the carboxylate group is slightly out of the plane of the parent benzene ring, the C—C—C—O torsion angles being 2.3 (2) and 2.0 (2)°. The carboxylate group and the hydroxy group form O—H⋯O hydrogen bonds, generating a head-to-tail chain...
Autores principales: | , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2011
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Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3152065/ https://www.ncbi.nlm.nih.gov/pubmed/21837161 http://dx.doi.org/10.1107/S1600536811024044 |
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author | Li, Heping Liu, Pei Yang, Yunxia |
author_facet | Li, Heping Liu, Pei Yang, Yunxia |
author_sort | Li, Heping |
collection | PubMed |
description | In the title compound, C(8)H(20)N(+)·C(7)H(5)O(3) (−)·H(2)O, the carboxylate group is slightly out of the plane of the parent benzene ring, the C—C—C—O torsion angles being 2.3 (2) and 2.0 (2)°. The carboxylate group and the hydroxy group form O—H⋯O hydrogen bonds, generating a head-to-tail chain along the b axis. Neighbouring hydrogen-bonded chains are linked by the water molecule, generating two independent O—H⋯O donor hydrogen bonds. The carboxylate group thus constructs a hydrogen-bonded host layer parallel to (10[Image: see text]). The tetraethylammonium cation is contained between these layers, forming a sandwich-like structure with an approximate interlayer distance of 10.03 Å. |
format | Online Article Text |
id | pubmed-3152065 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2011 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-31520652011-08-11 Tetraethylammonium 4-hydroxybenzoate monohydrate Li, Heping Liu, Pei Yang, Yunxia Acta Crystallogr Sect E Struct Rep Online Organic Papers In the title compound, C(8)H(20)N(+)·C(7)H(5)O(3) (−)·H(2)O, the carboxylate group is slightly out of the plane of the parent benzene ring, the C—C—C—O torsion angles being 2.3 (2) and 2.0 (2)°. The carboxylate group and the hydroxy group form O—H⋯O hydrogen bonds, generating a head-to-tail chain along the b axis. Neighbouring hydrogen-bonded chains are linked by the water molecule, generating two independent O—H⋯O donor hydrogen bonds. The carboxylate group thus constructs a hydrogen-bonded host layer parallel to (10[Image: see text]). The tetraethylammonium cation is contained between these layers, forming a sandwich-like structure with an approximate interlayer distance of 10.03 Å. International Union of Crystallography 2011-06-25 /pmc/articles/PMC3152065/ /pubmed/21837161 http://dx.doi.org/10.1107/S1600536811024044 Text en © Li et al. 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Organic Papers Li, Heping Liu, Pei Yang, Yunxia Tetraethylammonium 4-hydroxybenzoate monohydrate |
title | Tetraethylammonium 4-hydroxybenzoate monohydrate |
title_full | Tetraethylammonium 4-hydroxybenzoate monohydrate |
title_fullStr | Tetraethylammonium 4-hydroxybenzoate monohydrate |
title_full_unstemmed | Tetraethylammonium 4-hydroxybenzoate monohydrate |
title_short | Tetraethylammonium 4-hydroxybenzoate monohydrate |
title_sort | tetraethylammonium 4-hydroxybenzoate monohydrate |
topic | Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3152065/ https://www.ncbi.nlm.nih.gov/pubmed/21837161 http://dx.doi.org/10.1107/S1600536811024044 |
work_keys_str_mv | AT liheping tetraethylammonium4hydroxybenzoatemonohydrate AT liupei tetraethylammonium4hydroxybenzoatemonohydrate AT yangyunxia tetraethylammonium4hydroxybenzoatemonohydrate |