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N′-[(E)-1-(5-Bromo-2-hydroxyphenyl)ethylidene]-4-nitrobenzohydrazide
The title compound, C(15)H(12)BrN(3)O(4), displays a trans conformation with respect to the C=N double bond. The central atoms around the C=N double bond are not coplanar, in contrast to the aromatic rings, which exhibit a dihedral angle of 1.80 (4)° between their mean planes. An intramolecular O—H...
Autores principales: | , , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2011
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3152073/ https://www.ncbi.nlm.nih.gov/pubmed/21837180 http://dx.doi.org/10.1107/S1600536811023609 |
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author | Zheng, Chang-Zheng Wang, Liang Liu, Juan Wang, Yu-Jie |
author_facet | Zheng, Chang-Zheng Wang, Liang Liu, Juan Wang, Yu-Jie |
author_sort | Zheng, Chang-Zheng |
collection | PubMed |
description | The title compound, C(15)H(12)BrN(3)O(4), displays a trans conformation with respect to the C=N double bond. The central atoms around the C=N double bond are not coplanar, in contrast to the aromatic rings, which exhibit a dihedral angle of 1.80 (4)° between their mean planes. An intramolecular O—H⋯N hydrogen bond occurs. In the crystal, molecules are connected via intermolecular N—H⋯O hydrogen bonding into chains along the a axis. |
format | Online Article Text |
id | pubmed-3152073 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2011 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-31520732011-08-11 N′-[(E)-1-(5-Bromo-2-hydroxyphenyl)ethylidene]-4-nitrobenzohydrazide Zheng, Chang-Zheng Wang, Liang Liu, Juan Wang, Yu-Jie Acta Crystallogr Sect E Struct Rep Online Organic Papers The title compound, C(15)H(12)BrN(3)O(4), displays a trans conformation with respect to the C=N double bond. The central atoms around the C=N double bond are not coplanar, in contrast to the aromatic rings, which exhibit a dihedral angle of 1.80 (4)° between their mean planes. An intramolecular O—H⋯N hydrogen bond occurs. In the crystal, molecules are connected via intermolecular N—H⋯O hydrogen bonding into chains along the a axis. International Union of Crystallography 2011-06-25 /pmc/articles/PMC3152073/ /pubmed/21837180 http://dx.doi.org/10.1107/S1600536811023609 Text en © Zheng et al. 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Organic Papers Zheng, Chang-Zheng Wang, Liang Liu, Juan Wang, Yu-Jie N′-[(E)-1-(5-Bromo-2-hydroxyphenyl)ethylidene]-4-nitrobenzohydrazide |
title |
N′-[(E)-1-(5-Bromo-2-hydroxyphenyl)ethylidene]-4-nitrobenzohydrazide |
title_full |
N′-[(E)-1-(5-Bromo-2-hydroxyphenyl)ethylidene]-4-nitrobenzohydrazide |
title_fullStr |
N′-[(E)-1-(5-Bromo-2-hydroxyphenyl)ethylidene]-4-nitrobenzohydrazide |
title_full_unstemmed |
N′-[(E)-1-(5-Bromo-2-hydroxyphenyl)ethylidene]-4-nitrobenzohydrazide |
title_short |
N′-[(E)-1-(5-Bromo-2-hydroxyphenyl)ethylidene]-4-nitrobenzohydrazide |
title_sort | n′-[(e)-1-(5-bromo-2-hydroxyphenyl)ethylidene]-4-nitrobenzohydrazide |
topic | Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3152073/ https://www.ncbi.nlm.nih.gov/pubmed/21837180 http://dx.doi.org/10.1107/S1600536811023609 |
work_keys_str_mv | AT zhengchangzheng ne15bromo2hydroxyphenylethylidene4nitrobenzohydrazide AT wangliang ne15bromo2hydroxyphenylethylidene4nitrobenzohydrazide AT liujuan ne15bromo2hydroxyphenylethylidene4nitrobenzohydrazide AT wangyujie ne15bromo2hydroxyphenylethylidene4nitrobenzohydrazide |