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Bis[1-(4-cyanobenzyl)pyrazinium] bis(1,2-dicyanoethene-1,2-dithiolato)nickelate(II)
The asymmetric unit of the title complex, (C(12)H(10)N(3))(2)[Ni(C(4)N(2)S(2))(2)], consists of one 1-(4-cyanobenzyl)pyrazinium cation and one half of an [Ni(mnt)(2)](2−) dianion (mnt(2−) is 1,2-dicyanoethene-1,2-dithiolate). The Ni(2+) ion is located on an inversion center and is coordinated by...
Autores principales: | , , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2011
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3152075/ https://www.ncbi.nlm.nih.gov/pubmed/21836926 http://dx.doi.org/10.1107/S1600536811022550 |
Sumario: | The asymmetric unit of the title complex, (C(12)H(10)N(3))(2)[Ni(C(4)N(2)S(2))(2)], consists of one 1-(4-cyanobenzyl)pyrazinium cation and one half of an [Ni(mnt)(2)](2−) dianion (mnt(2−) is 1,2-dicyanoethene-1,2-dithiolate). The Ni(2+) ion is located on an inversion center and is coordinated by four S atoms from two mnt(2−) ligands, exhibiting a square-planar coordination geometry. The cation adopts a conformation where both the pyrazine ring and the benzene ring are twisted with respect to the C—C—N reference plane by 16.5 (2) and 69.8 (1)°, respectively. |
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