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Bis[1-(4-cyano­benz­yl)pyrazinium] bis­(1,2-dicyano­ethene-1,2-dithiol­ato)nickelate(II)

The asymmetric unit of the title complex, (C(12)H(10)N(3))(2)[Ni(C(4)N(2)S(2))(2)], consists of one 1-(4-cyano­benz­yl)pyrazinium cation and one half of an [Ni(mnt)(2)](2−) dianion (mnt(2−) is 1,2-dicyano­ethene-1,2-dithiol­ate). The Ni(2+) ion is located on an inversion center and is coordinated by...

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Detalles Bibliográficos
Autores principales: Zhang, Hui, Pei, Wen-Bo, Yu, Shan-Shan, Ren, Xiao-Ming
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2011
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3152075/
https://www.ncbi.nlm.nih.gov/pubmed/21836926
http://dx.doi.org/10.1107/S1600536811022550
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author Zhang, Hui
Pei, Wen-Bo
Yu, Shan-Shan
Ren, Xiao-Ming
author_facet Zhang, Hui
Pei, Wen-Bo
Yu, Shan-Shan
Ren, Xiao-Ming
author_sort Zhang, Hui
collection PubMed
description The asymmetric unit of the title complex, (C(12)H(10)N(3))(2)[Ni(C(4)N(2)S(2))(2)], consists of one 1-(4-cyano­benz­yl)pyrazinium cation and one half of an [Ni(mnt)(2)](2−) dianion (mnt(2−) is 1,2-dicyano­ethene-1,2-dithiol­ate). The Ni(2+) ion is located on an inversion center and is coordinated by four S atoms from two mnt(2−) ligands, exhibiting a square-planar coordination geometry. The cation adopts a conformation where both the pyrazine ring and the benzene ring are twisted with respect to the C—C—N reference plane by 16.5 (2) and 69.8 (1)°, respectively.
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spelling pubmed-31520752011-08-11 Bis[1-(4-cyano­benz­yl)pyrazinium] bis­(1,2-dicyano­ethene-1,2-dithiol­ato)nickelate(II) Zhang, Hui Pei, Wen-Bo Yu, Shan-Shan Ren, Xiao-Ming Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The asymmetric unit of the title complex, (C(12)H(10)N(3))(2)[Ni(C(4)N(2)S(2))(2)], consists of one 1-(4-cyano­benz­yl)pyrazinium cation and one half of an [Ni(mnt)(2)](2−) dianion (mnt(2−) is 1,2-dicyano­ethene-1,2-dithiol­ate). The Ni(2+) ion is located on an inversion center and is coordinated by four S atoms from two mnt(2−) ligands, exhibiting a square-planar coordination geometry. The cation adopts a conformation where both the pyrazine ring and the benzene ring are twisted with respect to the C—C—N reference plane by 16.5 (2) and 69.8 (1)°, respectively. International Union of Crystallography 2011-06-18 /pmc/articles/PMC3152075/ /pubmed/21836926 http://dx.doi.org/10.1107/S1600536811022550 Text en © Zhang et al. 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Zhang, Hui
Pei, Wen-Bo
Yu, Shan-Shan
Ren, Xiao-Ming
Bis[1-(4-cyano­benz­yl)pyrazinium] bis­(1,2-dicyano­ethene-1,2-dithiol­ato)nickelate(II)
title Bis[1-(4-cyano­benz­yl)pyrazinium] bis­(1,2-dicyano­ethene-1,2-dithiol­ato)nickelate(II)
title_full Bis[1-(4-cyano­benz­yl)pyrazinium] bis­(1,2-dicyano­ethene-1,2-dithiol­ato)nickelate(II)
title_fullStr Bis[1-(4-cyano­benz­yl)pyrazinium] bis­(1,2-dicyano­ethene-1,2-dithiol­ato)nickelate(II)
title_full_unstemmed Bis[1-(4-cyano­benz­yl)pyrazinium] bis­(1,2-dicyano­ethene-1,2-dithiol­ato)nickelate(II)
title_short Bis[1-(4-cyano­benz­yl)pyrazinium] bis­(1,2-dicyano­ethene-1,2-dithiol­ato)nickelate(II)
title_sort bis[1-(4-cyano­benz­yl)pyrazinium] bis­(1,2-dicyano­ethene-1,2-dithiol­ato)nickelate(ii)
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3152075/
https://www.ncbi.nlm.nih.gov/pubmed/21836926
http://dx.doi.org/10.1107/S1600536811022550
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