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Bis(1-methylpiperazine-1,4-diium) tetrachloridocuprate(II)
The title compound, (C(5)H(14)N(2))[CuCl(4)], was synthesized by hydrothermal reaction of CuCl(2) with 1-methylpiperazine in an HCl/water solution. Both amine N atoms are protonated. The piperazine ring adopts a chair conformation. The Cu—Cl distances in the tetrahedral anion are in the range 2.23...
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
International Union of Crystallography
2011
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| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3152076/ https://www.ncbi.nlm.nih.gov/pubmed/21836953 http://dx.doi.org/10.1107/S1600536811024354 |
| Sumario: | The title compound, (C(5)H(14)N(2))[CuCl(4)], was synthesized by hydrothermal reaction of CuCl(2) with 1-methylpiperazine in an HCl/water solution. Both amine N atoms are protonated. The piperazine ring adopts a chair conformation. The Cu—Cl distances in the tetrahedral anion are in the range 2.2360 (7)–2.2732 (7) Å. In the crystal, moderately strong and weak intermolecular N—H⋯Cl hydrogen bonds link the anion and cation units into an infinite two-dimensional network parallel to the ab plane. |
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