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Bis(1-methylpiperazine-1,4-diium) tetrachloridocuprate(II)
The title compound, (C(5)H(14)N(2))[CuCl(4)], was synthesized by hydrothermal reaction of CuCl(2) with 1-methylpiperazine in an HCl/water solution. Both amine N atoms are protonated. The piperazine ring adopts a chair conformation. The Cu—Cl distances in the tetrahedral anion are in the range 2.23...
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
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International Union of Crystallography
2011
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| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3152076/ https://www.ncbi.nlm.nih.gov/pubmed/21836953 http://dx.doi.org/10.1107/S1600536811024354 |
| _version_ | 1782209721831260160 |
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| author | Peng, Cong-hu |
| author_facet | Peng, Cong-hu |
| author_sort | Peng, Cong-hu |
| collection | PubMed |
| description | The title compound, (C(5)H(14)N(2))[CuCl(4)], was synthesized by hydrothermal reaction of CuCl(2) with 1-methylpiperazine in an HCl/water solution. Both amine N atoms are protonated. The piperazine ring adopts a chair conformation. The Cu—Cl distances in the tetrahedral anion are in the range 2.2360 (7)–2.2732 (7) Å. In the crystal, moderately strong and weak intermolecular N—H⋯Cl hydrogen bonds link the anion and cation units into an infinite two-dimensional network parallel to the ab plane. |
| format | Online Article Text |
| id | pubmed-3152076 |
| institution | National Center for Biotechnology Information |
| language | English |
| publishDate | 2011 |
| publisher | International Union of Crystallography |
| record_format | MEDLINE/PubMed |
| spelling | pubmed-31520762011-08-11 Bis(1-methylpiperazine-1,4-diium) tetrachloridocuprate(II) Peng, Cong-hu Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The title compound, (C(5)H(14)N(2))[CuCl(4)], was synthesized by hydrothermal reaction of CuCl(2) with 1-methylpiperazine in an HCl/water solution. Both amine N atoms are protonated. The piperazine ring adopts a chair conformation. The Cu—Cl distances in the tetrahedral anion are in the range 2.2360 (7)–2.2732 (7) Å. In the crystal, moderately strong and weak intermolecular N—H⋯Cl hydrogen bonds link the anion and cation units into an infinite two-dimensional network parallel to the ab plane. International Union of Crystallography 2011-06-25 /pmc/articles/PMC3152076/ /pubmed/21836953 http://dx.doi.org/10.1107/S1600536811024354 Text en © Cong-hu Peng 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
| spellingShingle | Metal-Organic Papers Peng, Cong-hu Bis(1-methylpiperazine-1,4-diium) tetrachloridocuprate(II) |
| title | Bis(1-methylpiperazine-1,4-diium) tetrachloridocuprate(II) |
| title_full | Bis(1-methylpiperazine-1,4-diium) tetrachloridocuprate(II) |
| title_fullStr | Bis(1-methylpiperazine-1,4-diium) tetrachloridocuprate(II) |
| title_full_unstemmed | Bis(1-methylpiperazine-1,4-diium) tetrachloridocuprate(II) |
| title_short | Bis(1-methylpiperazine-1,4-diium) tetrachloridocuprate(II) |
| title_sort | bis(1-methylpiperazine-1,4-diium) tetrachloridocuprate(ii) |
| topic | Metal-Organic Papers |
| url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3152076/ https://www.ncbi.nlm.nih.gov/pubmed/21836953 http://dx.doi.org/10.1107/S1600536811024354 |
| work_keys_str_mv | AT pengconghu bis1methylpiperazine14diiumtetrachloridocuprateii |