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Poly[[diaqua-μ(6)-succinato-di-μ(5)-succinato-didysprosium(III)] mono­hydrate]

The title compound, {[Dy(2)(C(4)H(4)O(4))(3)(H(2)O)(2)]·H(2)O}(n), is isostructural with other lanthanide succinates of the same formula. The Dy(III) atom is nine-coordinated in a tricapped trigonal–prismatic environment by eight O atoms, derived from six carboxyl­ate groups and a water mol­ecule. O...

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Detalles Bibliográficos
Autores principales: Xu, Wei, Chang, Hai-Sheng, Guo, Xia-Xia
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2011
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3152080/
https://www.ncbi.nlm.nih.gov/pubmed/21836969
http://dx.doi.org/10.1107/S1600536811024330
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author Xu, Wei
Chang, Hai-Sheng
Guo, Xia-Xia
author_facet Xu, Wei
Chang, Hai-Sheng
Guo, Xia-Xia
author_sort Xu, Wei
collection PubMed
description The title compound, {[Dy(2)(C(4)H(4)O(4))(3)(H(2)O)(2)]·H(2)O}(n), is isostructural with other lanthanide succinates of the same formula. The Dy(III) atom is nine-coordinated in a tricapped trigonal–prismatic environment by eight O atoms, derived from six carboxyl­ate groups and a water mol­ecule. One of the independent succinate anions is located about a crystallographic inversion center and the uncoordinated water mol­ecule lies on a twofold axis. The crystal structure comprises edge-shared DyO(9) polyhedra linked by succinate bridges, forming a three-dimensional network architecture. Intra- and inter­molecular O—H⋯O hydrogen bonds are present in the crystal structure.
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spelling pubmed-31520802011-08-11 Poly[[diaqua-μ(6)-succinato-di-μ(5)-succinato-didysprosium(III)] mono­hydrate] Xu, Wei Chang, Hai-Sheng Guo, Xia-Xia Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The title compound, {[Dy(2)(C(4)H(4)O(4))(3)(H(2)O)(2)]·H(2)O}(n), is isostructural with other lanthanide succinates of the same formula. The Dy(III) atom is nine-coordinated in a tricapped trigonal–prismatic environment by eight O atoms, derived from six carboxyl­ate groups and a water mol­ecule. One of the independent succinate anions is located about a crystallographic inversion center and the uncoordinated water mol­ecule lies on a twofold axis. The crystal structure comprises edge-shared DyO(9) polyhedra linked by succinate bridges, forming a three-dimensional network architecture. Intra- and inter­molecular O—H⋯O hydrogen bonds are present in the crystal structure. International Union of Crystallography 2011-06-30 /pmc/articles/PMC3152080/ /pubmed/21836969 http://dx.doi.org/10.1107/S1600536811024330 Text en © Xu et al. 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Xu, Wei
Chang, Hai-Sheng
Guo, Xia-Xia
Poly[[diaqua-μ(6)-succinato-di-μ(5)-succinato-didysprosium(III)] mono­hydrate]
title Poly[[diaqua-μ(6)-succinato-di-μ(5)-succinato-didysprosium(III)] mono­hydrate]
title_full Poly[[diaqua-μ(6)-succinato-di-μ(5)-succinato-didysprosium(III)] mono­hydrate]
title_fullStr Poly[[diaqua-μ(6)-succinato-di-μ(5)-succinato-didysprosium(III)] mono­hydrate]
title_full_unstemmed Poly[[diaqua-μ(6)-succinato-di-μ(5)-succinato-didysprosium(III)] mono­hydrate]
title_short Poly[[diaqua-μ(6)-succinato-di-μ(5)-succinato-didysprosium(III)] mono­hydrate]
title_sort poly[[diaqua-μ(6)-succinato-di-μ(5)-succinato-didysprosium(iii)] mono­hydrate]
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3152080/
https://www.ncbi.nlm.nih.gov/pubmed/21836969
http://dx.doi.org/10.1107/S1600536811024330
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