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catena-Poly[[[aqua­bis­(4,4′-bipyridine-κN)zinc]-μ-l-tyrosinato-κ(3) N,O (1):O (1′)] nitrate dihydrate]

In the title compound, {[Zn(C(9)H(10)NO(3))(C(10)H(8)N(2))(2)(H(2)O)]NO(3)·2H(2)O}(n), the Zn(II) atom is six-coordinated in a distorted octa­hedral geometry by two carboxyl­ate O atoms and one amino N atom from two l-tyrosinate ligands, two N atoms from two 4,4′-bipyridine ligands, and one water mo...

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Detalles Bibliográficos
Autores principales: Li, Shu-Qiang, Hu, Ning-Hai
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2011
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3152081/
https://www.ncbi.nlm.nih.gov/pubmed/21836877
http://dx.doi.org/10.1107/S1600536811021088
Descripción
Sumario:In the title compound, {[Zn(C(9)H(10)NO(3))(C(10)H(8)N(2))(2)(H(2)O)]NO(3)·2H(2)O}(n), the Zn(II) atom is six-coordinated in a distorted octa­hedral geometry by two carboxyl­ate O atoms and one amino N atom from two l-tyrosinate ligands, two N atoms from two 4,4′-bipyridine ligands, and one water mol­ecule. Adjacent Zn atoms are bridged by the bidentate carboxyl­ate groups into a cationic chain extending along [010]. N—H⋯N, O—H⋯N and O—H⋯O hydrogen bonds link the cationic chains, nitrate anions and uncoordinated water mol­ecules into a supra­molecular network. π–π inter­actions between the pyridine rings and between the pyridine and benzene rings [centroid–centroid distances = 3.615 (4) and 3.636 (4) Å] are present.