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catena-Poly[[[aquabis(4,4′-bipyridine-κN)zinc]-μ-l-tyrosinato-κ(3) N,O (1):O (1′)] nitrate dihydrate]
In the title compound, {[Zn(C(9)H(10)NO(3))(C(10)H(8)N(2))(2)(H(2)O)]NO(3)·2H(2)O}(n), the Zn(II) atom is six-coordinated in a distorted octahedral geometry by two carboxylate O atoms and one amino N atom from two l-tyrosinate ligands, two N atoms from two 4,4′-bipyridine ligands, and one water mo...
Autores principales: | , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2011
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3152081/ https://www.ncbi.nlm.nih.gov/pubmed/21836877 http://dx.doi.org/10.1107/S1600536811021088 |
Sumario: | In the title compound, {[Zn(C(9)H(10)NO(3))(C(10)H(8)N(2))(2)(H(2)O)]NO(3)·2H(2)O}(n), the Zn(II) atom is six-coordinated in a distorted octahedral geometry by two carboxylate O atoms and one amino N atom from two l-tyrosinate ligands, two N atoms from two 4,4′-bipyridine ligands, and one water molecule. Adjacent Zn atoms are bridged by the bidentate carboxylate groups into a cationic chain extending along [010]. N—H⋯N, O—H⋯N and O—H⋯O hydrogen bonds link the cationic chains, nitrate anions and uncoordinated water molecules into a supramolecular network. π–π interactions between the pyridine rings and between the pyridine and benzene rings [centroid–centroid distances = 3.615 (4) and 3.636 (4) Å] are present. |
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