Cargando…

catena-Poly[[[aqua­bis­(4,4′-bipyridine-κN)zinc]-μ-l-tyrosinato-κ(3) N,O (1):O (1′)] nitrate dihydrate]

In the title compound, {[Zn(C(9)H(10)NO(3))(C(10)H(8)N(2))(2)(H(2)O)]NO(3)·2H(2)O}(n), the Zn(II) atom is six-coordinated in a distorted octa­hedral geometry by two carboxyl­ate O atoms and one amino N atom from two l-tyrosinate ligands, two N atoms from two 4,4′-bipyridine ligands, and one water mo...

Descripción completa

Detalles Bibliográficos
Autores principales: Li, Shu-Qiang, Hu, Ning-Hai
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2011
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3152081/
https://www.ncbi.nlm.nih.gov/pubmed/21836877
http://dx.doi.org/10.1107/S1600536811021088
_version_ 1782209723072774144
author Li, Shu-Qiang
Hu, Ning-Hai
author_facet Li, Shu-Qiang
Hu, Ning-Hai
author_sort Li, Shu-Qiang
collection PubMed
description In the title compound, {[Zn(C(9)H(10)NO(3))(C(10)H(8)N(2))(2)(H(2)O)]NO(3)·2H(2)O}(n), the Zn(II) atom is six-coordinated in a distorted octa­hedral geometry by two carboxyl­ate O atoms and one amino N atom from two l-tyrosinate ligands, two N atoms from two 4,4′-bipyridine ligands, and one water mol­ecule. Adjacent Zn atoms are bridged by the bidentate carboxyl­ate groups into a cationic chain extending along [010]. N—H⋯N, O—H⋯N and O—H⋯O hydrogen bonds link the cationic chains, nitrate anions and uncoordinated water mol­ecules into a supra­molecular network. π–π inter­actions between the pyridine rings and between the pyridine and benzene rings [centroid–centroid distances = 3.615 (4) and 3.636 (4) Å] are present.
format Online
Article
Text
id pubmed-3152081
institution National Center for Biotechnology Information
language English
publishDate 2011
publisher International Union of Crystallography
record_format MEDLINE/PubMed
spelling pubmed-31520812011-08-11 catena-Poly[[[aqua­bis­(4,4′-bipyridine-κN)zinc]-μ-l-tyrosinato-κ(3) N,O (1):O (1′)] nitrate dihydrate] Li, Shu-Qiang Hu, Ning-Hai Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title compound, {[Zn(C(9)H(10)NO(3))(C(10)H(8)N(2))(2)(H(2)O)]NO(3)·2H(2)O}(n), the Zn(II) atom is six-coordinated in a distorted octa­hedral geometry by two carboxyl­ate O atoms and one amino N atom from two l-tyrosinate ligands, two N atoms from two 4,4′-bipyridine ligands, and one water mol­ecule. Adjacent Zn atoms are bridged by the bidentate carboxyl­ate groups into a cationic chain extending along [010]. N—H⋯N, O—H⋯N and O—H⋯O hydrogen bonds link the cationic chains, nitrate anions and uncoordinated water mol­ecules into a supra­molecular network. π–π inter­actions between the pyridine rings and between the pyridine and benzene rings [centroid–centroid distances = 3.615 (4) and 3.636 (4) Å] are present. International Union of Crystallography 2011-06-11 /pmc/articles/PMC3152081/ /pubmed/21836877 http://dx.doi.org/10.1107/S1600536811021088 Text en © Li and Hu 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Li, Shu-Qiang
Hu, Ning-Hai
catena-Poly[[[aqua­bis­(4,4′-bipyridine-κN)zinc]-μ-l-tyrosinato-κ(3) N,O (1):O (1′)] nitrate dihydrate]
title catena-Poly[[[aqua­bis­(4,4′-bipyridine-κN)zinc]-μ-l-tyrosinato-κ(3) N,O (1):O (1′)] nitrate dihydrate]
title_full catena-Poly[[[aqua­bis­(4,4′-bipyridine-κN)zinc]-μ-l-tyrosinato-κ(3) N,O (1):O (1′)] nitrate dihydrate]
title_fullStr catena-Poly[[[aqua­bis­(4,4′-bipyridine-κN)zinc]-μ-l-tyrosinato-κ(3) N,O (1):O (1′)] nitrate dihydrate]
title_full_unstemmed catena-Poly[[[aqua­bis­(4,4′-bipyridine-κN)zinc]-μ-l-tyrosinato-κ(3) N,O (1):O (1′)] nitrate dihydrate]
title_short catena-Poly[[[aqua­bis­(4,4′-bipyridine-κN)zinc]-μ-l-tyrosinato-κ(3) N,O (1):O (1′)] nitrate dihydrate]
title_sort catena-poly[[[aqua­bis­(4,4′-bipyridine-κn)zinc]-μ-l-tyrosinato-κ(3) n,o (1):o (1′)] nitrate dihydrate]
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3152081/
https://www.ncbi.nlm.nih.gov/pubmed/21836877
http://dx.doi.org/10.1107/S1600536811021088
work_keys_str_mv AT lishuqiang catenapolyaquabis44bipyridineknzincmltyrosinatok3no1o1nitratedihydrate
AT huninghai catenapolyaquabis44bipyridineknzincmltyrosinatok3no1o1nitratedihydrate