Tetra­butyl­ammonium 4-hy­droxy­benzoate dihydrate

In the title compound, (n-C(4)H(9))(4)N(+)·C(7)H(5)O(3) (−)·2H(2)O, the carboxyl­ate group is twisted slightly out of the plane of the attached benzene ring, the two C—C—C—O torsion angles being −8.9 (2) and −10.7 (2)°. The anion inter­acts with two water mol­ecules through several O—H⋯O hydrogen bo...

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Detalles Bibliográficos
Autores principales: Yang, Yuan, Yang, Yunxia
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2011
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3152085/
https://www.ncbi.nlm.nih.gov/pubmed/21837099
http://dx.doi.org/10.1107/S1600536811022823
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author Yang, Yuan
Yang, Yunxia
author_facet Yang, Yuan
Yang, Yunxia
author_sort Yang, Yuan
collection PubMed
description In the title compound, (n-C(4)H(9))(4)N(+)·C(7)H(5)O(3) (−)·2H(2)O, the carboxyl­ate group is twisted slightly out of the plane of the attached benzene ring, the two C—C—C—O torsion angles being −8.9 (2) and −10.7 (2)°. The anion inter­acts with two water mol­ecules through several O—H⋯O hydrogen bonds, forming wide ribbons along the a axis constructed from two anion–water chains. These ribbons are contained between unclosed diamond-like (16.2 × 15.0 Å) channels constructed by four rows of tetra­butyl­ammonium cations, which are arranged along the [011] and [01[Image: see text]] directions.
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spelling pubmed-31520852011-08-11 Tetra­butyl­ammonium 4-hy­droxy­benzoate dihydrate Yang, Yuan Yang, Yunxia Acta Crystallogr Sect E Struct Rep Online Organic Papers In the title compound, (n-C(4)H(9))(4)N(+)·C(7)H(5)O(3) (−)·2H(2)O, the carboxyl­ate group is twisted slightly out of the plane of the attached benzene ring, the two C—C—C—O torsion angles being −8.9 (2) and −10.7 (2)°. The anion inter­acts with two water mol­ecules through several O—H⋯O hydrogen bonds, forming wide ribbons along the a axis constructed from two anion–water chains. These ribbons are contained between unclosed diamond-like (16.2 × 15.0 Å) channels constructed by four rows of tetra­butyl­ammonium cations, which are arranged along the [011] and [01[Image: see text]] directions. International Union of Crystallography 2011-06-18 /pmc/articles/PMC3152085/ /pubmed/21837099 http://dx.doi.org/10.1107/S1600536811022823 Text en © Yang and Yang 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Yang, Yuan
Yang, Yunxia
Tetra­butyl­ammonium 4-hy­droxy­benzoate dihydrate
title Tetra­butyl­ammonium 4-hy­droxy­benzoate dihydrate
title_full Tetra­butyl­ammonium 4-hy­droxy­benzoate dihydrate
title_fullStr Tetra­butyl­ammonium 4-hy­droxy­benzoate dihydrate
title_full_unstemmed Tetra­butyl­ammonium 4-hy­droxy­benzoate dihydrate
title_short Tetra­butyl­ammonium 4-hy­droxy­benzoate dihydrate
title_sort tetra­butyl­ammonium 4-hy­droxy­benzoate dihydrate
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3152085/
https://www.ncbi.nlm.nih.gov/pubmed/21837099
http://dx.doi.org/10.1107/S1600536811022823
work_keys_str_mv AT yangyuan tetrabutylammonium4hydroxybenzoatedihydrate
AT yangyunxia tetrabutylammonium4hydroxybenzoatedihydrate

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