trans-Diaqua­bis­(1H-imidazole-4-carboxyl­ato-κ(2) N (3),O (4))nickel(II)

In the title complex, [Ni(C(4)H(3)N(2)O(2))(2)(H(2)O)(2)], the Ni(II) ion is located on an inversion center and shows a distorted octa­hedral geometry, defined by two N,O-bidentate 1H-imidazole-4-carboxyl­ate ligands in the equatorial plane and two water mol­ecules in the axial positions. Inter­mole...

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Detalles Bibliográficos
Autores principales: Zheng, Shengrun, Cai, Songliang, Fan, Jun, Zhang, Weiguang
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2011
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3152087/
https://www.ncbi.nlm.nih.gov/pubmed/21836862
http://dx.doi.org/10.1107/S1600536811018824
Descripción
Sumario:In the title complex, [Ni(C(4)H(3)N(2)O(2))(2)(H(2)O)(2)], the Ni(II) ion is located on an inversion center and shows a distorted octa­hedral geometry, defined by two N,O-bidentate 1H-imidazole-4-carboxyl­ate ligands in the equatorial plane and two water mol­ecules in the axial positions. Inter­molecular N—H⋯O hydrogen bonds link the complex mol­ecules into layers parallel to (10[Image: see text]), which are further linked into a three-dimensional supra­molecular network through O—H⋯O hydrogen bonds.

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