trans-Diaqua­bis­(1H-imidazole-4-carboxyl­ato-κ(2) N (3),O (4))nickel(II)

In the title complex, [Ni(C(4)H(3)N(2)O(2))(2)(H(2)O)(2)], the Ni(II) ion is located on an inversion center and shows a distorted octa­hedral geometry, defined by two N,O-bidentate 1H-imidazole-4-carboxyl­ate ligands in the equatorial plane and two water mol­ecules in the axial positions. Inter­mole...

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Detalles Bibliográficos
Autores principales: Zheng, Shengrun, Cai, Songliang, Fan, Jun, Zhang, Weiguang
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2011
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3152087/
https://www.ncbi.nlm.nih.gov/pubmed/21836862
http://dx.doi.org/10.1107/S1600536811018824
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author Zheng, Shengrun
Cai, Songliang
Fan, Jun
Zhang, Weiguang
author_facet Zheng, Shengrun
Cai, Songliang
Fan, Jun
Zhang, Weiguang
author_sort Zheng, Shengrun
collection PubMed
description In the title complex, [Ni(C(4)H(3)N(2)O(2))(2)(H(2)O)(2)], the Ni(II) ion is located on an inversion center and shows a distorted octa­hedral geometry, defined by two N,O-bidentate 1H-imidazole-4-carboxyl­ate ligands in the equatorial plane and two water mol­ecules in the axial positions. Inter­molecular N—H⋯O hydrogen bonds link the complex mol­ecules into layers parallel to (10[Image: see text]), which are further linked into a three-dimensional supra­molecular network through O—H⋯O hydrogen bonds.
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spelling pubmed-31520872011-08-11 trans-Diaqua­bis­(1H-imidazole-4-carboxyl­ato-κ(2) N (3),O (4))nickel(II) Zheng, Shengrun Cai, Songliang Fan, Jun Zhang, Weiguang Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title complex, [Ni(C(4)H(3)N(2)O(2))(2)(H(2)O)(2)], the Ni(II) ion is located on an inversion center and shows a distorted octa­hedral geometry, defined by two N,O-bidentate 1H-imidazole-4-carboxyl­ate ligands in the equatorial plane and two water mol­ecules in the axial positions. Inter­molecular N—H⋯O hydrogen bonds link the complex mol­ecules into layers parallel to (10[Image: see text]), which are further linked into a three-dimensional supra­molecular network through O—H⋯O hydrogen bonds. International Union of Crystallography 2011-06-11 /pmc/articles/PMC3152087/ /pubmed/21836862 http://dx.doi.org/10.1107/S1600536811018824 Text en © Zheng et al. 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Zheng, Shengrun
Cai, Songliang
Fan, Jun
Zhang, Weiguang
trans-Diaqua­bis­(1H-imidazole-4-carboxyl­ato-κ(2) N (3),O (4))nickel(II)
title trans-Diaqua­bis­(1H-imidazole-4-carboxyl­ato-κ(2) N (3),O (4))nickel(II)
title_full trans-Diaqua­bis­(1H-imidazole-4-carboxyl­ato-κ(2) N (3),O (4))nickel(II)
title_fullStr trans-Diaqua­bis­(1H-imidazole-4-carboxyl­ato-κ(2) N (3),O (4))nickel(II)
title_full_unstemmed trans-Diaqua­bis­(1H-imidazole-4-carboxyl­ato-κ(2) N (3),O (4))nickel(II)
title_short trans-Diaqua­bis­(1H-imidazole-4-carboxyl­ato-κ(2) N (3),O (4))nickel(II)
title_sort trans-diaqua­bis­(1h-imidazole-4-carboxyl­ato-κ(2) n (3),o (4))nickel(ii)
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3152087/
https://www.ncbi.nlm.nih.gov/pubmed/21836862
http://dx.doi.org/10.1107/S1600536811018824
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