Bis[3,3-dimethyl-2-(2-oxoethyl­idene)indolinyl-κ(2) N,O]palladium(II)

The asymmetric unit of the title compound, [Pd(C(12)H(12)NO)(2)], consists of three crystallographically independent half-mol­ecules. Each Pd(II) atom lies on a center of inversion and is four-coordinated by two monoanionic forms of the amino­acryl­aldehyde in a square-planar geometry. In the crysta...

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Detalles Bibliográficos
Autores principales: Khaledi, Hamid, Olmstead, Marilyn M., Mohd Ali, Hapipah
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2011
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3152092/
https://www.ncbi.nlm.nih.gov/pubmed/21836913
http://dx.doi.org/10.1107/S1600536811022069
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author Khaledi, Hamid
Olmstead, Marilyn M.
Mohd Ali, Hapipah
author_facet Khaledi, Hamid
Olmstead, Marilyn M.
Mohd Ali, Hapipah
author_sort Khaledi, Hamid
collection PubMed
description The asymmetric unit of the title compound, [Pd(C(12)H(12)NO)(2)], consists of three crystallographically independent half-mol­ecules. Each Pd(II) atom lies on a center of inversion and is four-coordinated by two monoanionic forms of the amino­acryl­aldehyde in a square-planar geometry. In the crystal, adjacent mol­ecules are connected through C—H⋯π and C—H⋯O inter­actions into a three-dimensional polymeric structure.
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spelling pubmed-31520922011-08-11 Bis[3,3-dimethyl-2-(2-oxoethyl­idene)indolinyl-κ(2) N,O]palladium(II) Khaledi, Hamid Olmstead, Marilyn M. Mohd Ali, Hapipah Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The asymmetric unit of the title compound, [Pd(C(12)H(12)NO)(2)], consists of three crystallographically independent half-mol­ecules. Each Pd(II) atom lies on a center of inversion and is four-coordinated by two monoanionic forms of the amino­acryl­aldehyde in a square-planar geometry. In the crystal, adjacent mol­ecules are connected through C—H⋯π and C—H⋯O inter­actions into a three-dimensional polymeric structure. International Union of Crystallography 2011-06-18 /pmc/articles/PMC3152092/ /pubmed/21836913 http://dx.doi.org/10.1107/S1600536811022069 Text en © Khaledi et al. 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Khaledi, Hamid
Olmstead, Marilyn M.
Mohd Ali, Hapipah
Bis[3,3-dimethyl-2-(2-oxoethyl­idene)indolinyl-κ(2) N,O]palladium(II)
title Bis[3,3-dimethyl-2-(2-oxoethyl­idene)indolinyl-κ(2) N,O]palladium(II)
title_full Bis[3,3-dimethyl-2-(2-oxoethyl­idene)indolinyl-κ(2) N,O]palladium(II)
title_fullStr Bis[3,3-dimethyl-2-(2-oxoethyl­idene)indolinyl-κ(2) N,O]palladium(II)
title_full_unstemmed Bis[3,3-dimethyl-2-(2-oxoethyl­idene)indolinyl-κ(2) N,O]palladium(II)
title_short Bis[3,3-dimethyl-2-(2-oxoethyl­idene)indolinyl-κ(2) N,O]palladium(II)
title_sort bis[3,3-dimethyl-2-(2-oxoethyl­idene)indolinyl-κ(2) n,o]palladium(ii)
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3152092/
https://www.ncbi.nlm.nih.gov/pubmed/21836913
http://dx.doi.org/10.1107/S1600536811022069
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