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1,1′-Di-tert-butyl-2,2′,3,3′,4,4′,5,5′-octa­ethyl-1,1′-bis­tannole

The title compound, [Sn(2)(C(4)H(9))(2)(C(12)H(20))(2)], has two 1-stannacyclo­penta­diene skeletons related by inversion symmetry located at the mid-point of the Sn—Sn bond [2.7682 (2) Å]. Thus, the asymmetric unit comprises one half-mol­ecule. The planarity of the stannacyclo­penta­diene ring is i...

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Detalles Bibliográficos
Autores principales: Kuwabara, Takuya, Saito, Masaichi
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2011
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3152095/
https://www.ncbi.nlm.nih.gov/pubmed/21836931
http://dx.doi.org/10.1107/S1600536811022951
Descripción
Sumario:The title compound, [Sn(2)(C(4)H(9))(2)(C(12)H(20))(2)], has two 1-stannacyclo­penta­diene skeletons related by inversion symmetry located at the mid-point of the Sn—Sn bond [2.7682 (2) Å]. Thus, the asymmetric unit comprises one half-mol­ecule. The planarity of the stannacyclo­penta­diene ring is illustrated by the dihedral angle of 0.3 (1)°, defined by the C(4) and C—Sn—C planes. To avoid steric repulsion, the two stannole rings are oriented in an anti fashion through the Sn—Sn bond. These structural features are similar to those of other bis­tannoles.