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1,1′-Di-tert-butyl-2,2′,3,3′,4,4′,5,5′-octaethyl-1,1′-bistannole
The title compound, [Sn(2)(C(4)H(9))(2)(C(12)H(20))(2)], has two 1-stannacyclopentadiene skeletons related by inversion symmetry located at the mid-point of the Sn—Sn bond [2.7682 (2) Å]. Thus, the asymmetric unit comprises one half-molecule. The planarity of the stannacyclopentadiene ring is i...
Autores principales: | , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2011
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3152095/ https://www.ncbi.nlm.nih.gov/pubmed/21836931 http://dx.doi.org/10.1107/S1600536811022951 |
Sumario: | The title compound, [Sn(2)(C(4)H(9))(2)(C(12)H(20))(2)], has two 1-stannacyclopentadiene skeletons related by inversion symmetry located at the mid-point of the Sn—Sn bond [2.7682 (2) Å]. Thus, the asymmetric unit comprises one half-molecule. The planarity of the stannacyclopentadiene ring is illustrated by the dihedral angle of 0.3 (1)°, defined by the C(4) and C—Sn—C planes. To avoid steric repulsion, the two stannole rings are oriented in an anti fashion through the Sn—Sn bond. These structural features are similar to those of other bistannoles. |
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