1,1′-Di-tert-butyl-2,2′,3,3′,4,4′,5,5′-octa­ethyl-1,1′-bis­tannole

The title compound, [Sn(2)(C(4)H(9))(2)(C(12)H(20))(2)], has two 1-stannacyclo­penta­diene skeletons related by inversion symmetry located at the mid-point of the Sn—Sn bond [2.7682 (2) Å]. Thus, the asymmetric unit comprises one half-mol­ecule. The planarity of the stannacyclo­penta­diene ring is i...

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Detalles Bibliográficos
Autores principales: Kuwabara, Takuya, Saito, Masaichi
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2011
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3152095/
https://www.ncbi.nlm.nih.gov/pubmed/21836931
http://dx.doi.org/10.1107/S1600536811022951
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author Kuwabara, Takuya
Saito, Masaichi
author_facet Kuwabara, Takuya
Saito, Masaichi
author_sort Kuwabara, Takuya
collection PubMed
description The title compound, [Sn(2)(C(4)H(9))(2)(C(12)H(20))(2)], has two 1-stannacyclo­penta­diene skeletons related by inversion symmetry located at the mid-point of the Sn—Sn bond [2.7682 (2) Å]. Thus, the asymmetric unit comprises one half-mol­ecule. The planarity of the stannacyclo­penta­diene ring is illustrated by the dihedral angle of 0.3 (1)°, defined by the C(4) and C—Sn—C planes. To avoid steric repulsion, the two stannole rings are oriented in an anti fashion through the Sn—Sn bond. These structural features are similar to those of other bis­tannoles.
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spelling pubmed-31520952011-08-11 1,1′-Di-tert-butyl-2,2′,3,3′,4,4′,5,5′-octa­ethyl-1,1′-bis­tannole Kuwabara, Takuya Saito, Masaichi Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The title compound, [Sn(2)(C(4)H(9))(2)(C(12)H(20))(2)], has two 1-stannacyclo­penta­diene skeletons related by inversion symmetry located at the mid-point of the Sn—Sn bond [2.7682 (2) Å]. Thus, the asymmetric unit comprises one half-mol­ecule. The planarity of the stannacyclo­penta­diene ring is illustrated by the dihedral angle of 0.3 (1)°, defined by the C(4) and C—Sn—C planes. To avoid steric repulsion, the two stannole rings are oriented in an anti fashion through the Sn—Sn bond. These structural features are similar to those of other bis­tannoles. International Union of Crystallography 2011-06-18 /pmc/articles/PMC3152095/ /pubmed/21836931 http://dx.doi.org/10.1107/S1600536811022951 Text en © Kuwabara and Saito 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Kuwabara, Takuya
Saito, Masaichi
1,1′-Di-tert-butyl-2,2′,3,3′,4,4′,5,5′-octa­ethyl-1,1′-bis­tannole
title 1,1′-Di-tert-butyl-2,2′,3,3′,4,4′,5,5′-octa­ethyl-1,1′-bis­tannole
title_full 1,1′-Di-tert-butyl-2,2′,3,3′,4,4′,5,5′-octa­ethyl-1,1′-bis­tannole
title_fullStr 1,1′-Di-tert-butyl-2,2′,3,3′,4,4′,5,5′-octa­ethyl-1,1′-bis­tannole
title_full_unstemmed 1,1′-Di-tert-butyl-2,2′,3,3′,4,4′,5,5′-octa­ethyl-1,1′-bis­tannole
title_short 1,1′-Di-tert-butyl-2,2′,3,3′,4,4′,5,5′-octa­ethyl-1,1′-bis­tannole
title_sort 1,1′-di-tert-butyl-2,2′,3,3′,4,4′,5,5′-octa­ethyl-1,1′-bis­tannole
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3152095/
https://www.ncbi.nlm.nih.gov/pubmed/21836931
http://dx.doi.org/10.1107/S1600536811022951
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AT saitomasaichi 11ditertbutyl22334455octaethyl11bistannole

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