Dimethyl­ammonium bis­(4-methyl­morpholin-4-ium) tetra­chloridozincate

The title compound, (C(2)H(8)N)(C(5)H(12)NO)[ZnCl(4)], was synthesized by hydro­thermal reaction of ZnCl(2) with 4-methyl­morpholine in a dimethyl­formamide solution. The asymmetric unit is composed of half a [ZnCl(4)](2−) anion, half a 4-methyl­morpholin-4-ium cation and half a dimethyl­ammonium ca...

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Detalles Bibliográficos
Autores principales: Zhang, Yan-wei, Wang, Yan-fei
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2011
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3152096/
https://www.ncbi.nlm.nih.gov/pubmed/21836834
http://dx.doi.org/10.1107/S1600536811025049
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author Zhang, Yan-wei
Wang, Yan-fei
author_facet Zhang, Yan-wei
Wang, Yan-fei
author_sort Zhang, Yan-wei
collection PubMed
description The title compound, (C(2)H(8)N)(C(5)H(12)NO)[ZnCl(4)], was synthesized by hydro­thermal reaction of ZnCl(2) with 4-methyl­morpholine in a dimethyl­formamide solution. The asymmetric unit is composed of half a [ZnCl(4)](2−) anion, half a 4-methyl­morpholin-4-ium cation and half a dimethyl­ammonium cation, all located on mirror planes parallel to ac. All the amine H atoms are involved in inter­molecular N—H⋯Cl hydrogen bonds, building up an infinite chain parallel to the c axis.
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spelling pubmed-31520962011-08-11 Dimethyl­ammonium bis­(4-methyl­morpholin-4-ium) tetra­chloridozincate Zhang, Yan-wei Wang, Yan-fei Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The title compound, (C(2)H(8)N)(C(5)H(12)NO)[ZnCl(4)], was synthesized by hydro­thermal reaction of ZnCl(2) with 4-methyl­morpholine in a dimethyl­formamide solution. The asymmetric unit is composed of half a [ZnCl(4)](2−) anion, half a 4-methyl­morpholin-4-ium cation and half a dimethyl­ammonium cation, all located on mirror planes parallel to ac. All the amine H atoms are involved in inter­molecular N—H⋯Cl hydrogen bonds, building up an infinite chain parallel to the c axis. International Union of Crystallography 2011-06-30 /pmc/articles/PMC3152096/ /pubmed/21836834 http://dx.doi.org/10.1107/S1600536811025049 Text en © Zhang and Wang 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Zhang, Yan-wei
Wang, Yan-fei
Dimethyl­ammonium bis­(4-methyl­morpholin-4-ium) tetra­chloridozincate
title Dimethyl­ammonium bis­(4-methyl­morpholin-4-ium) tetra­chloridozincate
title_full Dimethyl­ammonium bis­(4-methyl­morpholin-4-ium) tetra­chloridozincate
title_fullStr Dimethyl­ammonium bis­(4-methyl­morpholin-4-ium) tetra­chloridozincate
title_full_unstemmed Dimethyl­ammonium bis­(4-methyl­morpholin-4-ium) tetra­chloridozincate
title_short Dimethyl­ammonium bis­(4-methyl­morpholin-4-ium) tetra­chloridozincate
title_sort dimethyl­ammonium bis­(4-methyl­morpholin-4-ium) tetra­chloridozincate
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3152096/
https://www.ncbi.nlm.nih.gov/pubmed/21836834
http://dx.doi.org/10.1107/S1600536811025049
work_keys_str_mv AT zhangyanwei dimethylammoniumbis4methylmorpholin4iumtetrachloridozincate
AT wangyanfei dimethylammoniumbis4methylmorpholin4iumtetrachloridozincate

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