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catena-Poly[[[(1,10-phenanthroline-κ(2) N,N′)zinc]-μ-pyridine-2,3-dicarboxylato-κ(4) N,O (2):O (2′),O (3)] monohydrate]
In the title complex, {[Zn(C(7)H(3)NO(4))(C(12)H(8)N(2))]·H(2)O}(n), the Zn(II) ion is in a distorted octahedral environment, defined by two N atoms from a chelating 1,10-phenanthroline (phen) ligand and one N atom and three O atoms from two pyridine-2,3-dicarboxylate (2,3-pydc) ligands. The bridg...
Autores principales: | , , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2011
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3152098/ https://www.ncbi.nlm.nih.gov/pubmed/21836861 http://dx.doi.org/10.1107/S1600536811020344 |
Sumario: | In the title complex, {[Zn(C(7)H(3)NO(4))(C(12)H(8)N(2))]·H(2)O}(n), the Zn(II) ion is in a distorted octahedral environment, defined by two N atoms from a chelating 1,10-phenanthroline (phen) ligand and one N atom and three O atoms from two pyridine-2,3-dicarboxylate (2,3-pydc) ligands. The bridging 2,3-pydc ligands connect the Zn(II) ions into a chain extending along [010]. O—H⋯O hydrogen bonds between the uncoordinated water molecules and the uncoordinated carboxylate O atoms, as well as π–π interactions between the pyridine rings of the phen ligands [centroid–centroid distance = 3.557 (2) Å], are observed. |
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