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[3,3′-Dihy­droxy-3,3′-bis­(pyridin-3-yl-κN)-1,1′-(pyridine-2,6-di­yl)dipropan-1-one](nitrato-κ(2) O,O′)silver(I)

In the title compound, a new macrocyclic metal complex, [Ag(NO(3))(C(21)H(15)N(3)O(4))], all non-H atoms are in a close-to-planar geometry (except for the nitrate anion), with a maximum out-of-plane deviation of 0.327 (6) Å for a pyridine C atom. The dihedral angle between the least-squares plane th...

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Detalles Bibliográficos
Autores principales: Dong, Jian-Yu, You, Tian-Pa
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2011
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3152099/
https://www.ncbi.nlm.nih.gov/pubmed/21836892
http://dx.doi.org/10.1107/S1600536811020472
Descripción
Sumario:In the title compound, a new macrocyclic metal complex, [Ag(NO(3))(C(21)H(15)N(3)O(4))], all non-H atoms are in a close-to-planar geometry (except for the nitrate anion), with a maximum out-of-plane deviation of 0.327 (6) Å for a pyridine C atom. The dihedral angle between the least-squares plane through the [3,3′-dihy­droxy-3,3′-bis­(pyridin-3-yl)-1,1′-(pyridine-2,6-di­yl)dipropan-1-one]silver(I) fragment and the nitrate anion is 31.29 (13)°. The mol­ecular structure is stabilized by several inter- and intra­molecular O—H⋯O and C—H⋯O hydrogen bonds. The Ag(I) atom is coordinated by two pyridine N atoms and two O atoms of the nitrate anion in a geometry intermediate between tetrahedral and square-planar.