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[3,3′-Dihy­droxy-3,3′-bis­(pyridin-3-yl-κN)-1,1′-(pyridine-2,6-di­yl)dipropan-1-one](nitrato-κ(2) O,O′)silver(I)

In the title compound, a new macrocyclic metal complex, [Ag(NO(3))(C(21)H(15)N(3)O(4))], all non-H atoms are in a close-to-planar geometry (except for the nitrate anion), with a maximum out-of-plane deviation of 0.327 (6) Å for a pyridine C atom. The dihedral angle between the least-squares plane th...

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Detalles Bibliográficos
Autores principales: Dong, Jian-Yu, You, Tian-Pa
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2011
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3152099/
https://www.ncbi.nlm.nih.gov/pubmed/21836892
http://dx.doi.org/10.1107/S1600536811020472
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author Dong, Jian-Yu
You, Tian-Pa
author_facet Dong, Jian-Yu
You, Tian-Pa
author_sort Dong, Jian-Yu
collection PubMed
description In the title compound, a new macrocyclic metal complex, [Ag(NO(3))(C(21)H(15)N(3)O(4))], all non-H atoms are in a close-to-planar geometry (except for the nitrate anion), with a maximum out-of-plane deviation of 0.327 (6) Å for a pyridine C atom. The dihedral angle between the least-squares plane through the [3,3′-dihy­droxy-3,3′-bis­(pyridin-3-yl)-1,1′-(pyridine-2,6-di­yl)dipropan-1-one]silver(I) fragment and the nitrate anion is 31.29 (13)°. The mol­ecular structure is stabilized by several inter- and intra­molecular O—H⋯O and C—H⋯O hydrogen bonds. The Ag(I) atom is coordinated by two pyridine N atoms and two O atoms of the nitrate anion in a geometry intermediate between tetrahedral and square-planar.
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spelling pubmed-31520992011-08-11 [3,3′-Dihy­droxy-3,3′-bis­(pyridin-3-yl-κN)-1,1′-(pyridine-2,6-di­yl)dipropan-1-one](nitrato-κ(2) O,O′)silver(I) Dong, Jian-Yu You, Tian-Pa Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title compound, a new macrocyclic metal complex, [Ag(NO(3))(C(21)H(15)N(3)O(4))], all non-H atoms are in a close-to-planar geometry (except for the nitrate anion), with a maximum out-of-plane deviation of 0.327 (6) Å for a pyridine C atom. The dihedral angle between the least-squares plane through the [3,3′-dihy­droxy-3,3′-bis­(pyridin-3-yl)-1,1′-(pyridine-2,6-di­yl)dipropan-1-one]silver(I) fragment and the nitrate anion is 31.29 (13)°. The mol­ecular structure is stabilized by several inter- and intra­molecular O—H⋯O and C—H⋯O hydrogen bonds. The Ag(I) atom is coordinated by two pyridine N atoms and two O atoms of the nitrate anion in a geometry intermediate between tetrahedral and square-planar. International Union of Crystallography 2011-06-11 /pmc/articles/PMC3152099/ /pubmed/21836892 http://dx.doi.org/10.1107/S1600536811020472 Text en © Dong and You 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Dong, Jian-Yu
You, Tian-Pa
[3,3′-Dihy­droxy-3,3′-bis­(pyridin-3-yl-κN)-1,1′-(pyridine-2,6-di­yl)dipropan-1-one](nitrato-κ(2) O,O′)silver(I)
title [3,3′-Dihy­droxy-3,3′-bis­(pyridin-3-yl-κN)-1,1′-(pyridine-2,6-di­yl)dipropan-1-one](nitrato-κ(2) O,O′)silver(I)
title_full [3,3′-Dihy­droxy-3,3′-bis­(pyridin-3-yl-κN)-1,1′-(pyridine-2,6-di­yl)dipropan-1-one](nitrato-κ(2) O,O′)silver(I)
title_fullStr [3,3′-Dihy­droxy-3,3′-bis­(pyridin-3-yl-κN)-1,1′-(pyridine-2,6-di­yl)dipropan-1-one](nitrato-κ(2) O,O′)silver(I)
title_full_unstemmed [3,3′-Dihy­droxy-3,3′-bis­(pyridin-3-yl-κN)-1,1′-(pyridine-2,6-di­yl)dipropan-1-one](nitrato-κ(2) O,O′)silver(I)
title_short [3,3′-Dihy­droxy-3,3′-bis­(pyridin-3-yl-κN)-1,1′-(pyridine-2,6-di­yl)dipropan-1-one](nitrato-κ(2) O,O′)silver(I)
title_sort [3,3′-dihy­droxy-3,3′-bis­(pyridin-3-yl-κn)-1,1′-(pyridine-2,6-di­yl)dipropan-1-one](nitrato-κ(2) o,o′)silver(i)
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3152099/
https://www.ncbi.nlm.nih.gov/pubmed/21836892
http://dx.doi.org/10.1107/S1600536811020472
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AT youtianpa 33dihydroxy33bispyridin3ylkn11pyridine26diyldipropan1onenitratok2oosilveri