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[3,3′-Dihydroxy-3,3′-bis(pyridin-3-yl-κN)-1,1′-(pyridine-2,6-diyl)dipropan-1-one](nitrato-κ(2) O,O′)silver(I)
In the title compound, a new macrocyclic metal complex, [Ag(NO(3))(C(21)H(15)N(3)O(4))], all non-H atoms are in a close-to-planar geometry (except for the nitrate anion), with a maximum out-of-plane deviation of 0.327 (6) Å for a pyridine C atom. The dihedral angle between the least-squares plane th...
Autores principales: | , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2011
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3152099/ https://www.ncbi.nlm.nih.gov/pubmed/21836892 http://dx.doi.org/10.1107/S1600536811020472 |
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author | Dong, Jian-Yu You, Tian-Pa |
author_facet | Dong, Jian-Yu You, Tian-Pa |
author_sort | Dong, Jian-Yu |
collection | PubMed |
description | In the title compound, a new macrocyclic metal complex, [Ag(NO(3))(C(21)H(15)N(3)O(4))], all non-H atoms are in a close-to-planar geometry (except for the nitrate anion), with a maximum out-of-plane deviation of 0.327 (6) Å for a pyridine C atom. The dihedral angle between the least-squares plane through the [3,3′-dihydroxy-3,3′-bis(pyridin-3-yl)-1,1′-(pyridine-2,6-diyl)dipropan-1-one]silver(I) fragment and the nitrate anion is 31.29 (13)°. The molecular structure is stabilized by several inter- and intramolecular O—H⋯O and C—H⋯O hydrogen bonds. The Ag(I) atom is coordinated by two pyridine N atoms and two O atoms of the nitrate anion in a geometry intermediate between tetrahedral and square-planar. |
format | Online Article Text |
id | pubmed-3152099 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2011 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-31520992011-08-11 [3,3′-Dihydroxy-3,3′-bis(pyridin-3-yl-κN)-1,1′-(pyridine-2,6-diyl)dipropan-1-one](nitrato-κ(2) O,O′)silver(I) Dong, Jian-Yu You, Tian-Pa Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title compound, a new macrocyclic metal complex, [Ag(NO(3))(C(21)H(15)N(3)O(4))], all non-H atoms are in a close-to-planar geometry (except for the nitrate anion), with a maximum out-of-plane deviation of 0.327 (6) Å for a pyridine C atom. The dihedral angle between the least-squares plane through the [3,3′-dihydroxy-3,3′-bis(pyridin-3-yl)-1,1′-(pyridine-2,6-diyl)dipropan-1-one]silver(I) fragment and the nitrate anion is 31.29 (13)°. The molecular structure is stabilized by several inter- and intramolecular O—H⋯O and C—H⋯O hydrogen bonds. The Ag(I) atom is coordinated by two pyridine N atoms and two O atoms of the nitrate anion in a geometry intermediate between tetrahedral and square-planar. International Union of Crystallography 2011-06-11 /pmc/articles/PMC3152099/ /pubmed/21836892 http://dx.doi.org/10.1107/S1600536811020472 Text en © Dong and You 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Metal-Organic Papers Dong, Jian-Yu You, Tian-Pa [3,3′-Dihydroxy-3,3′-bis(pyridin-3-yl-κN)-1,1′-(pyridine-2,6-diyl)dipropan-1-one](nitrato-κ(2) O,O′)silver(I) |
title | [3,3′-Dihydroxy-3,3′-bis(pyridin-3-yl-κN)-1,1′-(pyridine-2,6-diyl)dipropan-1-one](nitrato-κ(2)
O,O′)silver(I) |
title_full | [3,3′-Dihydroxy-3,3′-bis(pyridin-3-yl-κN)-1,1′-(pyridine-2,6-diyl)dipropan-1-one](nitrato-κ(2)
O,O′)silver(I) |
title_fullStr | [3,3′-Dihydroxy-3,3′-bis(pyridin-3-yl-κN)-1,1′-(pyridine-2,6-diyl)dipropan-1-one](nitrato-κ(2)
O,O′)silver(I) |
title_full_unstemmed | [3,3′-Dihydroxy-3,3′-bis(pyridin-3-yl-κN)-1,1′-(pyridine-2,6-diyl)dipropan-1-one](nitrato-κ(2)
O,O′)silver(I) |
title_short | [3,3′-Dihydroxy-3,3′-bis(pyridin-3-yl-κN)-1,1′-(pyridine-2,6-diyl)dipropan-1-one](nitrato-κ(2)
O,O′)silver(I) |
title_sort | [3,3′-dihydroxy-3,3′-bis(pyridin-3-yl-κn)-1,1′-(pyridine-2,6-diyl)dipropan-1-one](nitrato-κ(2)
o,o′)silver(i) |
topic | Metal-Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3152099/ https://www.ncbi.nlm.nih.gov/pubmed/21836892 http://dx.doi.org/10.1107/S1600536811020472 |
work_keys_str_mv | AT dongjianyu 33dihydroxy33bispyridin3ylkn11pyridine26diyldipropan1onenitratok2oosilveri AT youtianpa 33dihydroxy33bispyridin3ylkn11pyridine26diyldipropan1onenitratok2oosilveri |