Ethyl 3,3,3-trifluoro-2-hy­droxy-2-(5-meth­oxy-1H-indol-3-yl)propionate

In the title compound, C(14)H(14)F(3)NO(4), the 3,3,3-trifluoro­pyruvate fragment has a syn configuration and is noncoplanar with the indole plane [dihedral angle = 84.87 (5)°]. In the crystal, mol­ecules form inversion-related dimers via pairs of inter­molecular O—H⋯O hydrogen bonds. These dimers a...

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Detalles Bibliográficos
Autores principales: Kadirova, Zukhra, Tolipov, Samat, Fedorovskiy, Oleg, Bakhtiyar, Ibragimov, Parpiev, Nusrat
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2011
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3152102/
https://www.ncbi.nlm.nih.gov/pubmed/21837025
http://dx.doi.org/10.1107/S1600536811021489
Descripción
Sumario:In the title compound, C(14)H(14)F(3)NO(4), the 3,3,3-trifluoro­pyruvate fragment has a syn configuration and is noncoplanar with the indole plane [dihedral angle = 84.87 (5)°]. In the crystal, mol­ecules form inversion-related dimers via pairs of inter­molecular O—H⋯O hydrogen bonds. These dimers are connected by inter­molecular N—H⋯O=C(CF(3)) hydrogen bonds to form a two-dimensional network structure.

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