Ethyl 3,3,3-trifluoro-2-hy­droxy-2-(5-meth­oxy-1H-indol-3-yl)propionate

In the title compound, C(14)H(14)F(3)NO(4), the 3,3,3-trifluoro­pyruvate fragment has a syn configuration and is noncoplanar with the indole plane [dihedral angle = 84.87 (5)°]. In the crystal, mol­ecules form inversion-related dimers via pairs of inter­molecular O—H⋯O hydrogen bonds. These dimers a...

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Detalles Bibliográficos
Autores principales: Kadirova, Zukhra, Tolipov, Samat, Fedorovskiy, Oleg, Bakhtiyar, Ibragimov, Parpiev, Nusrat
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2011
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3152102/
https://www.ncbi.nlm.nih.gov/pubmed/21837025
http://dx.doi.org/10.1107/S1600536811021489
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author Kadirova, Zukhra
Tolipov, Samat
Fedorovskiy, Oleg
Bakhtiyar, Ibragimov
Parpiev, Nusrat
author_facet Kadirova, Zukhra
Tolipov, Samat
Fedorovskiy, Oleg
Bakhtiyar, Ibragimov
Parpiev, Nusrat
author_sort Kadirova, Zukhra
collection PubMed
description In the title compound, C(14)H(14)F(3)NO(4), the 3,3,3-trifluoro­pyruvate fragment has a syn configuration and is noncoplanar with the indole plane [dihedral angle = 84.87 (5)°]. In the crystal, mol­ecules form inversion-related dimers via pairs of inter­molecular O—H⋯O hydrogen bonds. These dimers are connected by inter­molecular N—H⋯O=C(CF(3)) hydrogen bonds to form a two-dimensional network structure.
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spelling pubmed-31521022011-08-11 Ethyl 3,3,3-trifluoro-2-hy­droxy-2-(5-meth­oxy-1H-indol-3-yl)propionate Kadirova, Zukhra Tolipov, Samat Fedorovskiy, Oleg Bakhtiyar, Ibragimov Parpiev, Nusrat Acta Crystallogr Sect E Struct Rep Online Organic Papers In the title compound, C(14)H(14)F(3)NO(4), the 3,3,3-trifluoro­pyruvate fragment has a syn configuration and is noncoplanar with the indole plane [dihedral angle = 84.87 (5)°]. In the crystal, mol­ecules form inversion-related dimers via pairs of inter­molecular O—H⋯O hydrogen bonds. These dimers are connected by inter­molecular N—H⋯O=C(CF(3)) hydrogen bonds to form a two-dimensional network structure. International Union of Crystallography 2011-06-11 /pmc/articles/PMC3152102/ /pubmed/21837025 http://dx.doi.org/10.1107/S1600536811021489 Text en © Kadirova et al. 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Kadirova, Zukhra
Tolipov, Samat
Fedorovskiy, Oleg
Bakhtiyar, Ibragimov
Parpiev, Nusrat
Ethyl 3,3,3-trifluoro-2-hy­droxy-2-(5-meth­oxy-1H-indol-3-yl)propionate
title Ethyl 3,3,3-trifluoro-2-hy­droxy-2-(5-meth­oxy-1H-indol-3-yl)propionate
title_full Ethyl 3,3,3-trifluoro-2-hy­droxy-2-(5-meth­oxy-1H-indol-3-yl)propionate
title_fullStr Ethyl 3,3,3-trifluoro-2-hy­droxy-2-(5-meth­oxy-1H-indol-3-yl)propionate
title_full_unstemmed Ethyl 3,3,3-trifluoro-2-hy­droxy-2-(5-meth­oxy-1H-indol-3-yl)propionate
title_short Ethyl 3,3,3-trifluoro-2-hy­droxy-2-(5-meth­oxy-1H-indol-3-yl)propionate
title_sort ethyl 3,3,3-trifluoro-2-hy­droxy-2-(5-meth­oxy-1h-indol-3-yl)propionate
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3152102/
https://www.ncbi.nlm.nih.gov/pubmed/21837025
http://dx.doi.org/10.1107/S1600536811021489
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