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Bis(8-hy­droxy-2-methyl­quinolinium) bis­(pyridine-2,6-dicarboxyl­ato)­nickelate(II) methanol monosolvate monohydrate

In the title compound, (C(10)H(10)NO)(2)[Ni(C(7)H(3)NO(4))(2)]·CH(3)OH·H(2)O, the coordination geometry of the Ni(II) atom can be described as distorted octa­hedral. In the crystal, noncovalent inter­actions play an important role in the stabilization of the structure, involving O—H⋯O, N—H⋯O and wea...

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Detalles Bibliográficos
Autores principales: Aghabozorg, Hossein, Gholizadeh, Ahmad, Mirzaei, Masoud, Notash, Behrouz, Moshki, Niloofar
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2011
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3152105/
https://www.ncbi.nlm.nih.gov/pubmed/21836882
http://dx.doi.org/10.1107/S1600536811021015
Descripción
Sumario:In the title compound, (C(10)H(10)NO)(2)[Ni(C(7)H(3)NO(4))(2)]·CH(3)OH·H(2)O, the coordination geometry of the Ni(II) atom can be described as distorted octa­hedral. In the crystal, noncovalent inter­actions play an important role in the stabilization of the structure, involving O—H⋯O, N—H⋯O and weak C—H⋯O hydrogen bonds and π–π stacking inter­actions between the pyridine rings of the pyridine-2,6-dicarboxyl­ate ligands [centroid–centroid distance = 3.7138 (15) Å] and between the 8-hy­droxy-2-methyl­quinolinium cations [centroid–centroid distances = 3.6737 (15), 3.4434 (14), 3.6743 (15), 3.7541 (16), 3.5020 (15) and 3.7947 (15) Å].