Bis(8-hy­droxy-2-methyl­quinolinium) bis­(pyridine-2,6-dicarboxyl­ato)­nickelate(II) methanol monosolvate monohydrate

In the title compound, (C(10)H(10)NO)(2)[Ni(C(7)H(3)NO(4))(2)]·CH(3)OH·H(2)O, the coordination geometry of the Ni(II) atom can be described as distorted octa­hedral. In the crystal, noncovalent inter­actions play an important role in the stabilization of the structure, involving O—H⋯O, N—H⋯O and wea...

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Autores principales: Aghabozorg, Hossein, Gholizadeh, Ahmad, Mirzaei, Masoud, Notash, Behrouz, Moshki, Niloofar
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2011
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3152105/
https://www.ncbi.nlm.nih.gov/pubmed/21836882
http://dx.doi.org/10.1107/S1600536811021015
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author Aghabozorg, Hossein
Gholizadeh, Ahmad
Mirzaei, Masoud
Notash, Behrouz
Moshki, Niloofar
author_facet Aghabozorg, Hossein
Gholizadeh, Ahmad
Mirzaei, Masoud
Notash, Behrouz
Moshki, Niloofar
author_sort Aghabozorg, Hossein
collection PubMed
description In the title compound, (C(10)H(10)NO)(2)[Ni(C(7)H(3)NO(4))(2)]·CH(3)OH·H(2)O, the coordination geometry of the Ni(II) atom can be described as distorted octa­hedral. In the crystal, noncovalent inter­actions play an important role in the stabilization of the structure, involving O—H⋯O, N—H⋯O and weak C—H⋯O hydrogen bonds and π–π stacking inter­actions between the pyridine rings of the pyridine-2,6-dicarboxyl­ate ligands [centroid–centroid distance = 3.7138 (15) Å] and between the 8-hy­droxy-2-methyl­quinolinium cations [centroid–centroid distances = 3.6737 (15), 3.4434 (14), 3.6743 (15), 3.7541 (16), 3.5020 (15) and 3.7947 (15) Å].
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spelling pubmed-31521052011-08-11 Bis(8-hy­droxy-2-methyl­quinolinium) bis­(pyridine-2,6-dicarboxyl­ato)­nickelate(II) methanol monosolvate monohydrate Aghabozorg, Hossein Gholizadeh, Ahmad Mirzaei, Masoud Notash, Behrouz Moshki, Niloofar Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title compound, (C(10)H(10)NO)(2)[Ni(C(7)H(3)NO(4))(2)]·CH(3)OH·H(2)O, the coordination geometry of the Ni(II) atom can be described as distorted octa­hedral. In the crystal, noncovalent inter­actions play an important role in the stabilization of the structure, involving O—H⋯O, N—H⋯O and weak C—H⋯O hydrogen bonds and π–π stacking inter­actions between the pyridine rings of the pyridine-2,6-dicarboxyl­ate ligands [centroid–centroid distance = 3.7138 (15) Å] and between the 8-hy­droxy-2-methyl­quinolinium cations [centroid–centroid distances = 3.6737 (15), 3.4434 (14), 3.6743 (15), 3.7541 (16), 3.5020 (15) and 3.7947 (15) Å]. International Union of Crystallography 2011-06-11 /pmc/articles/PMC3152105/ /pubmed/21836882 http://dx.doi.org/10.1107/S1600536811021015 Text en © Aghabozorg et al. 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Aghabozorg, Hossein
Gholizadeh, Ahmad
Mirzaei, Masoud
Notash, Behrouz
Moshki, Niloofar
Bis(8-hy­droxy-2-methyl­quinolinium) bis­(pyridine-2,6-dicarboxyl­ato)­nickelate(II) methanol monosolvate monohydrate
title Bis(8-hy­droxy-2-methyl­quinolinium) bis­(pyridine-2,6-dicarboxyl­ato)­nickelate(II) methanol monosolvate monohydrate
title_full Bis(8-hy­droxy-2-methyl­quinolinium) bis­(pyridine-2,6-dicarboxyl­ato)­nickelate(II) methanol monosolvate monohydrate
title_fullStr Bis(8-hy­droxy-2-methyl­quinolinium) bis­(pyridine-2,6-dicarboxyl­ato)­nickelate(II) methanol monosolvate monohydrate
title_full_unstemmed Bis(8-hy­droxy-2-methyl­quinolinium) bis­(pyridine-2,6-dicarboxyl­ato)­nickelate(II) methanol monosolvate monohydrate
title_short Bis(8-hy­droxy-2-methyl­quinolinium) bis­(pyridine-2,6-dicarboxyl­ato)­nickelate(II) methanol monosolvate monohydrate
title_sort bis(8-hy­droxy-2-methyl­quinolinium) bis­(pyridine-2,6-dicarboxyl­ato)­nickelate(ii) methanol monosolvate monohydrate
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3152105/
https://www.ncbi.nlm.nih.gov/pubmed/21836882
http://dx.doi.org/10.1107/S1600536811021015
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