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catena-Poly[[(2,2′-dimethyl-4,4′-bi-1,3-thiazole-κ(2) N,N′)cadmium]-di-μ-bromido]
In the title coordination polymer, [CdBr(2)(C(8)H(8)N(2)S(2))](n), the Cd(II) atom is six-coordinated in a distorted octahedral geometry by two N atoms from a 2,2′-dimethyl-4,4′-bi-1,3-thiazole ligand and four bridging Br atoms. The bridging function of the Br atoms leads to a chain structure alon...
Autores principales: | , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2011
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3152112/ https://www.ncbi.nlm.nih.gov/pubmed/21836878 http://dx.doi.org/10.1107/S1600536811020861 |
Sumario: | In the title coordination polymer, [CdBr(2)(C(8)H(8)N(2)S(2))](n), the Cd(II) atom is six-coordinated in a distorted octahedral geometry by two N atoms from a 2,2′-dimethyl-4,4′-bi-1,3-thiazole ligand and four bridging Br atoms. The bridging function of the Br atoms leads to a chain structure along [100]. Interchain C—H⋯Br hydrogen bonds and π–π contacts between the thiazole rings [centroid–centroid distances = 3.810 (5) and 3.679 (5) Å] are observed. |
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