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catena-Poly[[(2,2′-dimethyl-4,4′-bi-1,3-thia­zole-κ(2) N,N′)cadmium]-di-μ-bromido]

In the title coordination polymer, [CdBr(2)(C(8)H(8)N(2)S(2))](n), the Cd(II) atom is six-coordinated in a distorted octa­hedral geometry by two N atoms from a 2,2′-dimethyl-4,4′-bi-1,3-thia­zole ligand and four bridging Br atoms. The bridging function of the Br atoms leads to a chain structure alon...

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Detalles Bibliográficos
Autores principales: Abedi, Anita, Rezaei, Forugh
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2011
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3152112/
https://www.ncbi.nlm.nih.gov/pubmed/21836878
http://dx.doi.org/10.1107/S1600536811020861
Descripción
Sumario:In the title coordination polymer, [CdBr(2)(C(8)H(8)N(2)S(2))](n), the Cd(II) atom is six-coordinated in a distorted octa­hedral geometry by two N atoms from a 2,2′-dimethyl-4,4′-bi-1,3-thia­zole ligand and four bridging Br atoms. The bridging function of the Br atoms leads to a chain structure along [100]. Inter­chain C—H⋯Br hydrogen bonds and π–π contacts between the thia­zole rings [centroid–centroid distances = 3.810 (5) and 3.679 (5) Å] are observed.