catena-Poly[[(2,2′-dimethyl-4,4′-bi-1,3-thia­zole-κ(2) N,N′)cadmium]-di-μ-bromido]

In the title coordination polymer, [CdBr(2)(C(8)H(8)N(2)S(2))](n), the Cd(II) atom is six-coordinated in a distorted octa­hedral geometry by two N atoms from a 2,2′-dimethyl-4,4′-bi-1,3-thia­zole ligand and four bridging Br atoms. The bridging function of the Br atoms leads to a chain structure alon...

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Detalles Bibliográficos
Autores principales: Abedi, Anita, Rezaei, Forugh
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2011
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3152112/
https://www.ncbi.nlm.nih.gov/pubmed/21836878
http://dx.doi.org/10.1107/S1600536811020861
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author Abedi, Anita
Rezaei, Forugh
author_facet Abedi, Anita
Rezaei, Forugh
author_sort Abedi, Anita
collection PubMed
description In the title coordination polymer, [CdBr(2)(C(8)H(8)N(2)S(2))](n), the Cd(II) atom is six-coordinated in a distorted octa­hedral geometry by two N atoms from a 2,2′-dimethyl-4,4′-bi-1,3-thia­zole ligand and four bridging Br atoms. The bridging function of the Br atoms leads to a chain structure along [100]. Inter­chain C—H⋯Br hydrogen bonds and π–π contacts between the thia­zole rings [centroid–centroid distances = 3.810 (5) and 3.679 (5) Å] are observed.
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spelling pubmed-31521122011-08-11 catena-Poly[[(2,2′-dimethyl-4,4′-bi-1,3-thia­zole-κ(2) N,N′)cadmium]-di-μ-bromido] Abedi, Anita Rezaei, Forugh Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title coordination polymer, [CdBr(2)(C(8)H(8)N(2)S(2))](n), the Cd(II) atom is six-coordinated in a distorted octa­hedral geometry by two N atoms from a 2,2′-dimethyl-4,4′-bi-1,3-thia­zole ligand and four bridging Br atoms. The bridging function of the Br atoms leads to a chain structure along [100]. Inter­chain C—H⋯Br hydrogen bonds and π–π contacts between the thia­zole rings [centroid–centroid distances = 3.810 (5) and 3.679 (5) Å] are observed. International Union of Crystallography 2011-06-11 /pmc/articles/PMC3152112/ /pubmed/21836878 http://dx.doi.org/10.1107/S1600536811020861 Text en © Abedi and Rezaei 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Abedi, Anita
Rezaei, Forugh
catena-Poly[[(2,2′-dimethyl-4,4′-bi-1,3-thia­zole-κ(2) N,N′)cadmium]-di-μ-bromido]
title catena-Poly[[(2,2′-dimethyl-4,4′-bi-1,3-thia­zole-κ(2) N,N′)cadmium]-di-μ-bromido]
title_full catena-Poly[[(2,2′-dimethyl-4,4′-bi-1,3-thia­zole-κ(2) N,N′)cadmium]-di-μ-bromido]
title_fullStr catena-Poly[[(2,2′-dimethyl-4,4′-bi-1,3-thia­zole-κ(2) N,N′)cadmium]-di-μ-bromido]
title_full_unstemmed catena-Poly[[(2,2′-dimethyl-4,4′-bi-1,3-thia­zole-κ(2) N,N′)cadmium]-di-μ-bromido]
title_short catena-Poly[[(2,2′-dimethyl-4,4′-bi-1,3-thia­zole-κ(2) N,N′)cadmium]-di-μ-bromido]
title_sort catena-poly[[(2,2′-dimethyl-4,4′-bi-1,3-thia­zole-κ(2) n,n′)cadmium]-di-μ-bromido]
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3152112/
https://www.ncbi.nlm.nih.gov/pubmed/21836878
http://dx.doi.org/10.1107/S1600536811020861
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