Cyclo­benzaprinium salicylate

In the title mol­ecular salt [systematic name: 3-(5H-di­benzo[a,d]cyclo­hepten-5-yl­idene)-N,N-dimethyl-1-propanaminium 2-hy­droxy­benzoate], C(20)H(22)N(+)·C(7)H(5)O(3) (−), the benzene rings of the cyclo­benzaprinium cation are inclined with a dihedral angle of 61.66 (7)°. An intra­molecular O—H⋯O...

Descripción completa

Detalles Bibliográficos
Autores principales: Fun, Hoong-Kun, Yeap, Chin Sing, Siddegowda, M. S., Yathirajan, H. S., Narayana, B.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2011
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3152117/
https://www.ncbi.nlm.nih.gov/pubmed/21836993
http://dx.doi.org/10.1107/S1600536811020642
_version_ 1782209731246424064
author Fun, Hoong-Kun
Yeap, Chin Sing
Siddegowda, M. S.
Yathirajan, H. S.
Narayana, B.
author_facet Fun, Hoong-Kun
Yeap, Chin Sing
Siddegowda, M. S.
Yathirajan, H. S.
Narayana, B.
author_sort Fun, Hoong-Kun
collection PubMed
description In the title mol­ecular salt [systematic name: 3-(5H-di­benzo[a,d]cyclo­hepten-5-yl­idene)-N,N-dimethyl-1-propanaminium 2-hy­droxy­benzoate], C(20)H(22)N(+)·C(7)H(5)O(3) (−), the benzene rings of the cyclo­benzaprinium cation are inclined with a dihedral angle of 61.66 (7)°. An intra­molecular O—H⋯O hydrogen bond occurs within the salicylate anion, generating an S(6) ring. In the crystal, the cation and anion are linked by an N—H⋯O inter­action.
format Online
Article
Text
id pubmed-3152117
institution National Center for Biotechnology Information
language English
publishDate 2011
publisher International Union of Crystallography
record_format MEDLINE/PubMed
spelling pubmed-31521172011-08-11 Cyclo­benzaprinium salicylate Fun, Hoong-Kun Yeap, Chin Sing Siddegowda, M. S. Yathirajan, H. S. Narayana, B. Acta Crystallogr Sect E Struct Rep Online Organic Papers In the title mol­ecular salt [systematic name: 3-(5H-di­benzo[a,d]cyclo­hepten-5-yl­idene)-N,N-dimethyl-1-propanaminium 2-hy­droxy­benzoate], C(20)H(22)N(+)·C(7)H(5)O(3) (−), the benzene rings of the cyclo­benzaprinium cation are inclined with a dihedral angle of 61.66 (7)°. An intra­molecular O—H⋯O hydrogen bond occurs within the salicylate anion, generating an S(6) ring. In the crystal, the cation and anion are linked by an N—H⋯O inter­action. International Union of Crystallography 2011-06-04 /pmc/articles/PMC3152117/ /pubmed/21836993 http://dx.doi.org/10.1107/S1600536811020642 Text en © Fun et al. 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Fun, Hoong-Kun
Yeap, Chin Sing
Siddegowda, M. S.
Yathirajan, H. S.
Narayana, B.
Cyclo­benzaprinium salicylate
title Cyclo­benzaprinium salicylate
title_full Cyclo­benzaprinium salicylate
title_fullStr Cyclo­benzaprinium salicylate
title_full_unstemmed Cyclo­benzaprinium salicylate
title_short Cyclo­benzaprinium salicylate
title_sort cyclo­benzaprinium salicylate
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3152117/
https://www.ncbi.nlm.nih.gov/pubmed/21836993
http://dx.doi.org/10.1107/S1600536811020642
work_keys_str_mv AT funhoongkun cyclobenzapriniumsalicylate
AT yeapchinsing cyclobenzapriniumsalicylate
AT siddegowdams cyclobenzapriniumsalicylate
AT yathirajanhs cyclobenzapriniumsalicylate
AT narayanab cyclobenzapriniumsalicylate

Ejemplares similares