Redetermination of μ-oxido-bis­[bis­(N,N-diethyl­hydroxyl­aminato)­oxido­vanadium(V)]

In comparison with the previous determination [Saussine, Mimoun, Mitschler & Fisher (1980 ▶). Nouv. J. Chim. 4, 235–237] of the title compound, [V(2)(C(4)H(10)NO)(4)O(3)], the current study reports an improved precision of the derived geometric parameters, along with the deposition of all coordi...

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Detalles Bibliográficos
Autores principales: Zhang, Heng-Qiang, Jin, Zhong-Min, Fan, Xin, Zhang, Qi-Ying
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2011
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3152121/
https://www.ncbi.nlm.nih.gov/pubmed/21836859
http://dx.doi.org/10.1107/S1600536811020551
Descripción
Sumario:In comparison with the previous determination [Saussine, Mimoun, Mitschler & Fisher (1980 ▶). Nouv. J. Chim. 4, 235–237] of the title compound, [V(2)(C(4)H(10)NO)(4)O(3)], the current study reports an improved precision of the derived geometric parameters, along with the deposition of all coordinates and displacement parameters. The two V(V) atoms are each surrounded by two deprotonated N,O-bidentate diethyl­hydroxy­laminate groups, and a terminal and a bridging oxide ligand, in a distorted octa­hedral coordination geometry. The crystal packing is accomplished by van der Waals inter­actions.

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