Redetermination of μ-oxido-bis­[bis­(N,N-diethyl­hydroxyl­aminato)­oxido­vanadium(V)]

In comparison with the previous determination [Saussine, Mimoun, Mitschler & Fisher (1980 ▶). Nouv. J. Chim. 4, 235–237] of the title compound, [V(2)(C(4)H(10)NO)(4)O(3)], the current study reports an improved precision of the derived geometric parameters, along with the deposition of all coordi...

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Detalles Bibliográficos
Autores principales: Zhang, Heng-Qiang, Jin, Zhong-Min, Fan, Xin, Zhang, Qi-Ying
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2011
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3152121/
https://www.ncbi.nlm.nih.gov/pubmed/21836859
http://dx.doi.org/10.1107/S1600536811020551
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author Zhang, Heng-Qiang
Jin, Zhong-Min
Fan, Xin
Zhang, Qi-Ying
author_facet Zhang, Heng-Qiang
Jin, Zhong-Min
Fan, Xin
Zhang, Qi-Ying
author_sort Zhang, Heng-Qiang
collection PubMed
description In comparison with the previous determination [Saussine, Mimoun, Mitschler & Fisher (1980 ▶). Nouv. J. Chim. 4, 235–237] of the title compound, [V(2)(C(4)H(10)NO)(4)O(3)], the current study reports an improved precision of the derived geometric parameters, along with the deposition of all coordinates and displacement parameters. The two V(V) atoms are each surrounded by two deprotonated N,O-bidentate diethyl­hydroxy­laminate groups, and a terminal and a bridging oxide ligand, in a distorted octa­hedral coordination geometry. The crystal packing is accomplished by van der Waals inter­actions.
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spelling pubmed-31521212011-08-11 Redetermination of μ-oxido-bis­[bis­(N,N-diethyl­hydroxyl­aminato)­oxido­vanadium(V)] Zhang, Heng-Qiang Jin, Zhong-Min Fan, Xin Zhang, Qi-Ying Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In comparison with the previous determination [Saussine, Mimoun, Mitschler & Fisher (1980 ▶). Nouv. J. Chim. 4, 235–237] of the title compound, [V(2)(C(4)H(10)NO)(4)O(3)], the current study reports an improved precision of the derived geometric parameters, along with the deposition of all coordinates and displacement parameters. The two V(V) atoms are each surrounded by two deprotonated N,O-bidentate diethyl­hydroxy­laminate groups, and a terminal and a bridging oxide ligand, in a distorted octa­hedral coordination geometry. The crystal packing is accomplished by van der Waals inter­actions. International Union of Crystallography 2011-06-04 /pmc/articles/PMC3152121/ /pubmed/21836859 http://dx.doi.org/10.1107/S1600536811020551 Text en © Zhang et al. 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Zhang, Heng-Qiang
Jin, Zhong-Min
Fan, Xin
Zhang, Qi-Ying
Redetermination of μ-oxido-bis­[bis­(N,N-diethyl­hydroxyl­aminato)­oxido­vanadium(V)]
title Redetermination of μ-oxido-bis­[bis­(N,N-diethyl­hydroxyl­aminato)­oxido­vanadium(V)]
title_full Redetermination of μ-oxido-bis­[bis­(N,N-diethyl­hydroxyl­aminato)­oxido­vanadium(V)]
title_fullStr Redetermination of μ-oxido-bis­[bis­(N,N-diethyl­hydroxyl­aminato)­oxido­vanadium(V)]
title_full_unstemmed Redetermination of μ-oxido-bis­[bis­(N,N-diethyl­hydroxyl­aminato)­oxido­vanadium(V)]
title_short Redetermination of μ-oxido-bis­[bis­(N,N-diethyl­hydroxyl­aminato)­oxido­vanadium(V)]
title_sort redetermination of μ-oxido-bis­[bis­(n,n-diethyl­hydroxyl­aminato)­oxido­vanadium(v)]
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3152121/
https://www.ncbi.nlm.nih.gov/pubmed/21836859
http://dx.doi.org/10.1107/S1600536811020551
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