Diethyl 4,5-diphenyl-3,6-bis­(trimethyl­sil­yl)benzene-1,2-dicarboxyl­ate

In the title compound, C(30)H(38)O(4)Si(2), the two phenyl rings are twisted away from the central benzene ring by 70.28 (8) and 67.42 (7)°. The two Si atoms attached to the benzene ring deviate in opposite directions from the ring plane by 0.258 (3) and 0.206 (3) Å, respectively. One ethyl group is...

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Detalles Bibliográficos
Autores principales: Zhang, Jing, Qu, Hongmei, Zhang, Zhenyu, Zhou, Lishan
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2011
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3152123/
https://www.ncbi.nlm.nih.gov/pubmed/21837228
http://dx.doi.org/10.1107/S160053681102397X
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author Zhang, Jing
Qu, Hongmei
Zhang, Zhenyu
Zhou, Lishan
author_facet Zhang, Jing
Qu, Hongmei
Zhang, Zhenyu
Zhou, Lishan
author_sort Zhang, Jing
collection PubMed
description In the title compound, C(30)H(38)O(4)Si(2), the two phenyl rings are twisted away from the central benzene ring by 70.28 (8) and 67.42 (7)°. The two Si atoms attached to the benzene ring deviate in opposite directions from the ring plane by 0.258 (3) and 0.206 (3) Å, respectively. One ethyl group is disordered over two conformations in a 0.568 (5):0.432 (5) ratio. The crystal packing exhibits weak inter­molecular C—H⋯O inter­actions.
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spelling pubmed-31521232011-08-11 Diethyl 4,5-diphenyl-3,6-bis­(trimethyl­sil­yl)benzene-1,2-dicarboxyl­ate Zhang, Jing Qu, Hongmei Zhang, Zhenyu Zhou, Lishan Acta Crystallogr Sect E Struct Rep Online Organic Papers In the title compound, C(30)H(38)O(4)Si(2), the two phenyl rings are twisted away from the central benzene ring by 70.28 (8) and 67.42 (7)°. The two Si atoms attached to the benzene ring deviate in opposite directions from the ring plane by 0.258 (3) and 0.206 (3) Å, respectively. One ethyl group is disordered over two conformations in a 0.568 (5):0.432 (5) ratio. The crystal packing exhibits weak inter­molecular C—H⋯O inter­actions. International Union of Crystallography 2011-06-30 /pmc/articles/PMC3152123/ /pubmed/21837228 http://dx.doi.org/10.1107/S160053681102397X Text en © Zhang et al. 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Zhang, Jing
Qu, Hongmei
Zhang, Zhenyu
Zhou, Lishan
Diethyl 4,5-diphenyl-3,6-bis­(trimethyl­sil­yl)benzene-1,2-dicarboxyl­ate
title Diethyl 4,5-diphenyl-3,6-bis­(trimethyl­sil­yl)benzene-1,2-dicarboxyl­ate
title_full Diethyl 4,5-diphenyl-3,6-bis­(trimethyl­sil­yl)benzene-1,2-dicarboxyl­ate
title_fullStr Diethyl 4,5-diphenyl-3,6-bis­(trimethyl­sil­yl)benzene-1,2-dicarboxyl­ate
title_full_unstemmed Diethyl 4,5-diphenyl-3,6-bis­(trimethyl­sil­yl)benzene-1,2-dicarboxyl­ate
title_short Diethyl 4,5-diphenyl-3,6-bis­(trimethyl­sil­yl)benzene-1,2-dicarboxyl­ate
title_sort diethyl 4,5-diphenyl-3,6-bis­(trimethyl­sil­yl)benzene-1,2-dicarboxyl­ate
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3152123/
https://www.ncbi.nlm.nih.gov/pubmed/21837228
http://dx.doi.org/10.1107/S160053681102397X
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