(5R)-5-[(1R)-2,2-Dichloro-1-methyl­cyclo­prop­yl]-2-methyl­cyclo­hex-2-en-1-one

The title compound, C(11)H(14)Cl(2)O, was synthesized by the reaction of a dichloro­methane solution of (R)-carvone and potassium tert-butano­late in the presence of a catalytic amount of benzyl­triethyl­ammonium chloride in chloro­form. The cyclo­hexene ring adopts a half-boat conformation. The cyc...

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Autores principales: Boualy, Brahim, Harrad, Mohamed Anoir, El Firdoussi, Larbi, Ali, Mustapha Ait, Rizzoli, Corrado
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2011
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3152127/
https://www.ncbi.nlm.nih.gov/pubmed/21837043
http://dx.doi.org/10.1107/S1600536811021933
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author Boualy, Brahim
Harrad, Mohamed Anoir
El Firdoussi, Larbi
Ali, Mustapha Ait
Rizzoli, Corrado
author_facet Boualy, Brahim
Harrad, Mohamed Anoir
El Firdoussi, Larbi
Ali, Mustapha Ait
Rizzoli, Corrado
author_sort Boualy, Brahim
collection PubMed
description The title compound, C(11)H(14)Cl(2)O, was synthesized by the reaction of a dichloro­methane solution of (R)-carvone and potassium tert-butano­late in the presence of a catalytic amount of benzyl­triethyl­ammonium chloride in chloro­form. The cyclo­hexene ring adopts a half-boat conformation. The cyclo­propyl ring is unsymmetrical, the shortest C—C bond being distal to the alkyl-substituted C atom. The crystal packing is stabilized only by van der Waals inter­actions.
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spelling pubmed-31521272011-08-11 (5R)-5-[(1R)-2,2-Dichloro-1-methyl­cyclo­prop­yl]-2-methyl­cyclo­hex-2-en-1-one Boualy, Brahim Harrad, Mohamed Anoir El Firdoussi, Larbi Ali, Mustapha Ait Rizzoli, Corrado Acta Crystallogr Sect E Struct Rep Online Organic Papers The title compound, C(11)H(14)Cl(2)O, was synthesized by the reaction of a dichloro­methane solution of (R)-carvone and potassium tert-butano­late in the presence of a catalytic amount of benzyl­triethyl­ammonium chloride in chloro­form. The cyclo­hexene ring adopts a half-boat conformation. The cyclo­propyl ring is unsymmetrical, the shortest C—C bond being distal to the alkyl-substituted C atom. The crystal packing is stabilized only by van der Waals inter­actions. International Union of Crystallography 2011-06-11 /pmc/articles/PMC3152127/ /pubmed/21837043 http://dx.doi.org/10.1107/S1600536811021933 Text en © Boualy et al. 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Boualy, Brahim
Harrad, Mohamed Anoir
El Firdoussi, Larbi
Ali, Mustapha Ait
Rizzoli, Corrado
(5R)-5-[(1R)-2,2-Dichloro-1-methyl­cyclo­prop­yl]-2-methyl­cyclo­hex-2-en-1-one
title (5R)-5-[(1R)-2,2-Dichloro-1-methyl­cyclo­prop­yl]-2-methyl­cyclo­hex-2-en-1-one
title_full (5R)-5-[(1R)-2,2-Dichloro-1-methyl­cyclo­prop­yl]-2-methyl­cyclo­hex-2-en-1-one
title_fullStr (5R)-5-[(1R)-2,2-Dichloro-1-methyl­cyclo­prop­yl]-2-methyl­cyclo­hex-2-en-1-one
title_full_unstemmed (5R)-5-[(1R)-2,2-Dichloro-1-methyl­cyclo­prop­yl]-2-methyl­cyclo­hex-2-en-1-one
title_short (5R)-5-[(1R)-2,2-Dichloro-1-methyl­cyclo­prop­yl]-2-methyl­cyclo­hex-2-en-1-one
title_sort (5r)-5-[(1r)-2,2-dichloro-1-methyl­cyclo­prop­yl]-2-methyl­cyclo­hex-2-en-1-one
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3152127/
https://www.ncbi.nlm.nih.gov/pubmed/21837043
http://dx.doi.org/10.1107/S1600536811021933
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