3-Nitroso-2,4,6,8-tetra­phenyl-3,7-diaza­bicyclo­[3.3.1]nonan-9-one

In the title compound, C(31)H(27)N(3)O(2), the two piperidine rings fused to each other each adopt a slightly distorted chair conformation. The phenyl rings on the N-unsubstituted piperidine ring occupy an equatorial position, while those on the N-nitroso-substituted piperidine ring are in axial pos...

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Detalles Bibliográficos
Autores principales: Natarajan, Sampath, Mathews, Rita
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2011
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3152129/
https://www.ncbi.nlm.nih.gov/pubmed/21837083
http://dx.doi.org/10.1107/S1600536811022203
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author Natarajan, Sampath
Mathews, Rita
author_facet Natarajan, Sampath
Mathews, Rita
author_sort Natarajan, Sampath
collection PubMed
description In the title compound, C(31)H(27)N(3)O(2), the two piperidine rings fused to each other each adopt a slightly distorted chair conformation. The phenyl rings on the N-unsubstituted piperidine ring occupy an equatorial position, while those on the N-nitroso-substituted piperidine ring are in axial positions. The NO group is approximately coplanar with the piperidine ring with a maximum deviation of 0.048 (4) Å. The dihedral angles between the mean planes of the axially and equatorially oriented phenyl rings are 27.7 (1) and 31.9 (1)°, respectively. Mol­ecular packing is stabilized by weak inter­molecular C—H⋯O and C—H⋯π inter­actions.
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spelling pubmed-31521292011-08-11 3-Nitroso-2,4,6,8-tetra­phenyl-3,7-diaza­bicyclo­[3.3.1]nonan-9-one Natarajan, Sampath Mathews, Rita Acta Crystallogr Sect E Struct Rep Online Organic Papers In the title compound, C(31)H(27)N(3)O(2), the two piperidine rings fused to each other each adopt a slightly distorted chair conformation. The phenyl rings on the N-unsubstituted piperidine ring occupy an equatorial position, while those on the N-nitroso-substituted piperidine ring are in axial positions. The NO group is approximately coplanar with the piperidine ring with a maximum deviation of 0.048 (4) Å. The dihedral angles between the mean planes of the axially and equatorially oriented phenyl rings are 27.7 (1) and 31.9 (1)°, respectively. Mol­ecular packing is stabilized by weak inter­molecular C—H⋯O and C—H⋯π inter­actions. International Union of Crystallography 2011-06-18 /pmc/articles/PMC3152129/ /pubmed/21837083 http://dx.doi.org/10.1107/S1600536811022203 Text en © Natarajan and Mathews 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Natarajan, Sampath
Mathews, Rita
3-Nitroso-2,4,6,8-tetra­phenyl-3,7-diaza­bicyclo­[3.3.1]nonan-9-one
title 3-Nitroso-2,4,6,8-tetra­phenyl-3,7-diaza­bicyclo­[3.3.1]nonan-9-one
title_full 3-Nitroso-2,4,6,8-tetra­phenyl-3,7-diaza­bicyclo­[3.3.1]nonan-9-one
title_fullStr 3-Nitroso-2,4,6,8-tetra­phenyl-3,7-diaza­bicyclo­[3.3.1]nonan-9-one
title_full_unstemmed 3-Nitroso-2,4,6,8-tetra­phenyl-3,7-diaza­bicyclo­[3.3.1]nonan-9-one
title_short 3-Nitroso-2,4,6,8-tetra­phenyl-3,7-diaza­bicyclo­[3.3.1]nonan-9-one
title_sort 3-nitroso-2,4,6,8-tetra­phenyl-3,7-diaza­bicyclo­[3.3.1]nonan-9-one
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3152129/
https://www.ncbi.nlm.nih.gov/pubmed/21837083
http://dx.doi.org/10.1107/S1600536811022203
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