3,3′-[1,2-Phenyl­enebis(methyl­ene)]bis­(1-heptyl­benzimidazolium) dibromide monohydrate

In the title salt, C(36)H(48)N(4) (2+)·2Br(−)·H(2)O, the central benzene ring makes dihedral angles of 84.77 (9) and 69.92 (7)° with the adjacent imidazole rings. In the crystal, one of the heptyl groups is disordered over two sets of sites with an occupancy ratio of 0.474 (5):0.526 (5). In the crys...

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Detalles Bibliográficos
Autores principales: Haque, Rosenani A., Iqbal, Muhammad Adnan, Hemamalini, Madhukar, Fun, Hoong-Kun
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2011
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3152130/
https://www.ncbi.nlm.nih.gov/pubmed/21837184
http://dx.doi.org/10.1107/S1600536811023476
Descripción
Sumario:In the title salt, C(36)H(48)N(4) (2+)·2Br(−)·H(2)O, the central benzene ring makes dihedral angles of 84.77 (9) and 69.92 (7)° with the adjacent imidazole rings. In the crystal, one of the heptyl groups is disordered over two sets of sites with an occupancy ratio of 0.474 (5):0.526 (5). In the crystal, the cations, anions and water mol­ecules are connected via inter­molecular O—H⋯Br, C—H⋯Br and C—H⋯O hydrogen bonds, forming a three-dimensional network.

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