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N (4),N (4′)-Bis(4-methoxybenzylidene)-3,3′-dimethylbenzidine
The molecule of the title compund, C(30)H(28)N(2)O(2), a Schiff base synthesised via a condensation reaction between 4-methoxybenzaldehyde and 3,3′-dimethylbenzidine, a crystallographic twofold rotation axis passes through the mid-point of the C—C bond of the biphenyl unit. Thus, the asymmetric...
Autores principales: | , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2011
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3152131/ https://www.ncbi.nlm.nih.gov/pubmed/21837136 http://dx.doi.org/10.1107/S1600536811023749 |
Sumario: | The molecule of the title compund, C(30)H(28)N(2)O(2), a Schiff base synthesised via a condensation reaction between 4-methoxybenzaldehyde and 3,3′-dimethylbenzidine, a crystallographic twofold rotation axis passes through the mid-point of the C—C bond of the biphenyl unit. Thus, the asymmetric unit comprises one half-molecule. In the biphenyl unit, the aromatic rings are twisted by 13.49 (7)° with respect to one another. The dihedral angles between the biphenyl and methoxybenzene rings are 49.95 (12) and 50.06 (12)°. In the crystal, weak intermolecular C—H⋯ O hydrogen bonds contribute to the stabilization of the packing. |
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