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Poly[[diaquadi-μ(2)-cyanido-bis­(μ(2)-pyrazine-2-carboxyl­ato)dicopper(I)copper(II)] dihydrate]

In the title compound, {[Cu(II)Cu(I) (2)(C(5)H(3)N(2)O(2))(2)(CN)(2)(H(2)O)(2)]·2H(2)O}(n), the Cu(II) atom lies on an inversion centre and is octa­hedrally coordinated by two N atoms and two O atoms from opposing pyrazine-2-carboxyl­ate (2-pac) ligands and two water O atoms. The Cu(I) atom has a tr...

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Detalles Bibliográficos
Autores principales: Fan, Guang, Sun, Jia-juan, Zheng, Min-yan, Chen, San-ping, Gao, Sheng-Li
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2011
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3152133/
https://www.ncbi.nlm.nih.gov/pubmed/21836835
http://dx.doi.org/10.1107/S1600536811019453
Descripción
Sumario:In the title compound, {[Cu(II)Cu(I) (2)(C(5)H(3)N(2)O(2))(2)(CN)(2)(H(2)O)(2)]·2H(2)O}(n), the Cu(II) atom lies on an inversion centre and is octa­hedrally coordinated by two N atoms and two O atoms from opposing pyrazine-2-carboxyl­ate (2-pac) ligands and two water O atoms. The Cu(I) atom has a triangular geometry, coordinated by one N atom and one C atom from two bridging cyanide ligands, and another N atom from the 2-pac ligand. The three-dimensional structure features a succession of two-dimensional sheets containing [Cu(CN)](n) chains linked by Cu(2-pac)(2)(H(2)O)(2) groups. The coordinated and free water mol­ecules are involved in an extended three-dimensional hydrogen-bond network with the 2-pac ligands.