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Poly[[diaquadi-μ(2)-cyanido-bis­(μ(2)-pyrazine-2-carboxyl­ato)dicopper(I)copper(II)] dihydrate]

In the title compound, {[Cu(II)Cu(I) (2)(C(5)H(3)N(2)O(2))(2)(CN)(2)(H(2)O)(2)]·2H(2)O}(n), the Cu(II) atom lies on an inversion centre and is octa­hedrally coordinated by two N atoms and two O atoms from opposing pyrazine-2-carboxyl­ate (2-pac) ligands and two water O atoms. The Cu(I) atom has a tr...

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Autores principales: Fan, Guang, Sun, Jia-juan, Zheng, Min-yan, Chen, San-ping, Gao, Sheng-Li
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2011
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3152133/
https://www.ncbi.nlm.nih.gov/pubmed/21836835
http://dx.doi.org/10.1107/S1600536811019453
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author Fan, Guang
Sun, Jia-juan
Zheng, Min-yan
Chen, San-ping
Gao, Sheng-Li
author_facet Fan, Guang
Sun, Jia-juan
Zheng, Min-yan
Chen, San-ping
Gao, Sheng-Li
author_sort Fan, Guang
collection PubMed
description In the title compound, {[Cu(II)Cu(I) (2)(C(5)H(3)N(2)O(2))(2)(CN)(2)(H(2)O)(2)]·2H(2)O}(n), the Cu(II) atom lies on an inversion centre and is octa­hedrally coordinated by two N atoms and two O atoms from opposing pyrazine-2-carboxyl­ate (2-pac) ligands and two water O atoms. The Cu(I) atom has a triangular geometry, coordinated by one N atom and one C atom from two bridging cyanide ligands, and another N atom from the 2-pac ligand. The three-dimensional structure features a succession of two-dimensional sheets containing [Cu(CN)](n) chains linked by Cu(2-pac)(2)(H(2)O)(2) groups. The coordinated and free water mol­ecules are involved in an extended three-dimensional hydrogen-bond network with the 2-pac ligands.
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spelling pubmed-31521332011-08-11 Poly[[diaquadi-μ(2)-cyanido-bis­(μ(2)-pyrazine-2-carboxyl­ato)dicopper(I)copper(II)] dihydrate] Fan, Guang Sun, Jia-juan Zheng, Min-yan Chen, San-ping Gao, Sheng-Li Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title compound, {[Cu(II)Cu(I) (2)(C(5)H(3)N(2)O(2))(2)(CN)(2)(H(2)O)(2)]·2H(2)O}(n), the Cu(II) atom lies on an inversion centre and is octa­hedrally coordinated by two N atoms and two O atoms from opposing pyrazine-2-carboxyl­ate (2-pac) ligands and two water O atoms. The Cu(I) atom has a triangular geometry, coordinated by one N atom and one C atom from two bridging cyanide ligands, and another N atom from the 2-pac ligand. The three-dimensional structure features a succession of two-dimensional sheets containing [Cu(CN)](n) chains linked by Cu(2-pac)(2)(H(2)O)(2) groups. The coordinated and free water mol­ecules are involved in an extended three-dimensional hydrogen-bond network with the 2-pac ligands. International Union of Crystallography 2011-06-04 /pmc/articles/PMC3152133/ /pubmed/21836835 http://dx.doi.org/10.1107/S1600536811019453 Text en © Fan et al. 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Fan, Guang
Sun, Jia-juan
Zheng, Min-yan
Chen, San-ping
Gao, Sheng-Li
Poly[[diaquadi-μ(2)-cyanido-bis­(μ(2)-pyrazine-2-carboxyl­ato)dicopper(I)copper(II)] dihydrate]
title Poly[[diaquadi-μ(2)-cyanido-bis­(μ(2)-pyrazine-2-carboxyl­ato)dicopper(I)copper(II)] dihydrate]
title_full Poly[[diaquadi-μ(2)-cyanido-bis­(μ(2)-pyrazine-2-carboxyl­ato)dicopper(I)copper(II)] dihydrate]
title_fullStr Poly[[diaquadi-μ(2)-cyanido-bis­(μ(2)-pyrazine-2-carboxyl­ato)dicopper(I)copper(II)] dihydrate]
title_full_unstemmed Poly[[diaquadi-μ(2)-cyanido-bis­(μ(2)-pyrazine-2-carboxyl­ato)dicopper(I)copper(II)] dihydrate]
title_short Poly[[diaquadi-μ(2)-cyanido-bis­(μ(2)-pyrazine-2-carboxyl­ato)dicopper(I)copper(II)] dihydrate]
title_sort poly[[diaquadi-μ(2)-cyanido-bis­(μ(2)-pyrazine-2-carboxyl­ato)dicopper(i)copper(ii)] dihydrate]
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3152133/
https://www.ncbi.nlm.nih.gov/pubmed/21836835
http://dx.doi.org/10.1107/S1600536811019453
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