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Poly[[diaquadi-μ(2)-cyanido-bis(μ(2)-pyrazine-2-carboxylato)dicopper(I)copper(II)] dihydrate]
In the title compound, {[Cu(II)Cu(I) (2)(C(5)H(3)N(2)O(2))(2)(CN)(2)(H(2)O)(2)]·2H(2)O}(n), the Cu(II) atom lies on an inversion centre and is octahedrally coordinated by two N atoms and two O atoms from opposing pyrazine-2-carboxylate (2-pac) ligands and two water O atoms. The Cu(I) atom has a tr...
Autores principales: | , , , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2011
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3152133/ https://www.ncbi.nlm.nih.gov/pubmed/21836835 http://dx.doi.org/10.1107/S1600536811019453 |
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author | Fan, Guang Sun, Jia-juan Zheng, Min-yan Chen, San-ping Gao, Sheng-Li |
author_facet | Fan, Guang Sun, Jia-juan Zheng, Min-yan Chen, San-ping Gao, Sheng-Li |
author_sort | Fan, Guang |
collection | PubMed |
description | In the title compound, {[Cu(II)Cu(I) (2)(C(5)H(3)N(2)O(2))(2)(CN)(2)(H(2)O)(2)]·2H(2)O}(n), the Cu(II) atom lies on an inversion centre and is octahedrally coordinated by two N atoms and two O atoms from opposing pyrazine-2-carboxylate (2-pac) ligands and two water O atoms. The Cu(I) atom has a triangular geometry, coordinated by one N atom and one C atom from two bridging cyanide ligands, and another N atom from the 2-pac ligand. The three-dimensional structure features a succession of two-dimensional sheets containing [Cu(CN)](n) chains linked by Cu(2-pac)(2)(H(2)O)(2) groups. The coordinated and free water molecules are involved in an extended three-dimensional hydrogen-bond network with the 2-pac ligands. |
format | Online Article Text |
id | pubmed-3152133 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2011 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-31521332011-08-11 Poly[[diaquadi-μ(2)-cyanido-bis(μ(2)-pyrazine-2-carboxylato)dicopper(I)copper(II)] dihydrate] Fan, Guang Sun, Jia-juan Zheng, Min-yan Chen, San-ping Gao, Sheng-Li Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title compound, {[Cu(II)Cu(I) (2)(C(5)H(3)N(2)O(2))(2)(CN)(2)(H(2)O)(2)]·2H(2)O}(n), the Cu(II) atom lies on an inversion centre and is octahedrally coordinated by two N atoms and two O atoms from opposing pyrazine-2-carboxylate (2-pac) ligands and two water O atoms. The Cu(I) atom has a triangular geometry, coordinated by one N atom and one C atom from two bridging cyanide ligands, and another N atom from the 2-pac ligand. The three-dimensional structure features a succession of two-dimensional sheets containing [Cu(CN)](n) chains linked by Cu(2-pac)(2)(H(2)O)(2) groups. The coordinated and free water molecules are involved in an extended three-dimensional hydrogen-bond network with the 2-pac ligands. International Union of Crystallography 2011-06-04 /pmc/articles/PMC3152133/ /pubmed/21836835 http://dx.doi.org/10.1107/S1600536811019453 Text en © Fan et al. 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Metal-Organic Papers Fan, Guang Sun, Jia-juan Zheng, Min-yan Chen, San-ping Gao, Sheng-Li Poly[[diaquadi-μ(2)-cyanido-bis(μ(2)-pyrazine-2-carboxylato)dicopper(I)copper(II)] dihydrate] |
title | Poly[[diaquadi-μ(2)-cyanido-bis(μ(2)-pyrazine-2-carboxylato)dicopper(I)copper(II)] dihydrate] |
title_full | Poly[[diaquadi-μ(2)-cyanido-bis(μ(2)-pyrazine-2-carboxylato)dicopper(I)copper(II)] dihydrate] |
title_fullStr | Poly[[diaquadi-μ(2)-cyanido-bis(μ(2)-pyrazine-2-carboxylato)dicopper(I)copper(II)] dihydrate] |
title_full_unstemmed | Poly[[diaquadi-μ(2)-cyanido-bis(μ(2)-pyrazine-2-carboxylato)dicopper(I)copper(II)] dihydrate] |
title_short | Poly[[diaquadi-μ(2)-cyanido-bis(μ(2)-pyrazine-2-carboxylato)dicopper(I)copper(II)] dihydrate] |
title_sort | poly[[diaquadi-μ(2)-cyanido-bis(μ(2)-pyrazine-2-carboxylato)dicopper(i)copper(ii)] dihydrate] |
topic | Metal-Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3152133/ https://www.ncbi.nlm.nih.gov/pubmed/21836835 http://dx.doi.org/10.1107/S1600536811019453 |
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