Diazido­{(S)-1-phenyl-N,N-bis­[(2-pyrid­yl)meth­yl]ethanamine}­copper(II)

In the title compound, [Cu(N(3))(2)(C(20)H(21)N(3))], the Cu(II) ion is coordinated by the three N atoms of the (S)-1-phenyl-N,N-bis­[(2-pyrid­yl)meth­yl]ethanamine ligand and two N atoms from two azide anions, resulting in a distorted square-pyramidal environment. A weak inter­molecular C—H⋯N hydro...

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Detalles Bibliográficos
Autores principales: Rowthu, Sankara Rao, Shin, Jong Won, Kim, Seung-Hui, Kim, Jong Jin, Min, Kil Sik
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2011
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3152144/
https://www.ncbi.nlm.nih.gov/pubmed/21836869
http://dx.doi.org/10.1107/S1600536811021234
Descripción
Sumario:In the title compound, [Cu(N(3))(2)(C(20)H(21)N(3))], the Cu(II) ion is coordinated by the three N atoms of the (S)-1-phenyl-N,N-bis­[(2-pyrid­yl)meth­yl]ethanamine ligand and two N atoms from two azide anions, resulting in a distorted square-pyramidal environment. A weak inter­molecular C—H⋯N hydrogen-bonding inter­action between one pyridine group of the ligand and an azide N atom of an adjacent complex unit gives a one-dimensional chain structure parallel to the c axis.

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