Diazido­{(S)-1-phenyl-N,N-bis­[(2-pyrid­yl)meth­yl]ethanamine}­copper(II)

In the title compound, [Cu(N(3))(2)(C(20)H(21)N(3))], the Cu(II) ion is coordinated by the three N atoms of the (S)-1-phenyl-N,N-bis­[(2-pyrid­yl)meth­yl]ethanamine ligand and two N atoms from two azide anions, resulting in a distorted square-pyramidal environment. A weak inter­molecular C—H⋯N hydro...

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Detalles Bibliográficos
Autores principales: Rowthu, Sankara Rao, Shin, Jong Won, Kim, Seung-Hui, Kim, Jong Jin, Min, Kil Sik
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2011
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3152144/
https://www.ncbi.nlm.nih.gov/pubmed/21836869
http://dx.doi.org/10.1107/S1600536811021234
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author Rowthu, Sankara Rao
Shin, Jong Won
Kim, Seung-Hui
Kim, Jong Jin
Min, Kil Sik
author_facet Rowthu, Sankara Rao
Shin, Jong Won
Kim, Seung-Hui
Kim, Jong Jin
Min, Kil Sik
author_sort Rowthu, Sankara Rao
collection PubMed
description In the title compound, [Cu(N(3))(2)(C(20)H(21)N(3))], the Cu(II) ion is coordinated by the three N atoms of the (S)-1-phenyl-N,N-bis­[(2-pyrid­yl)meth­yl]ethanamine ligand and two N atoms from two azide anions, resulting in a distorted square-pyramidal environment. A weak inter­molecular C—H⋯N hydrogen-bonding inter­action between one pyridine group of the ligand and an azide N atom of an adjacent complex unit gives a one-dimensional chain structure parallel to the c axis.
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spelling pubmed-31521442011-08-11 Diazido­{(S)-1-phenyl-N,N-bis­[(2-pyrid­yl)meth­yl]ethanamine}­copper(II) Rowthu, Sankara Rao Shin, Jong Won Kim, Seung-Hui Kim, Jong Jin Min, Kil Sik Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title compound, [Cu(N(3))(2)(C(20)H(21)N(3))], the Cu(II) ion is coordinated by the three N atoms of the (S)-1-phenyl-N,N-bis­[(2-pyrid­yl)meth­yl]ethanamine ligand and two N atoms from two azide anions, resulting in a distorted square-pyramidal environment. A weak inter­molecular C—H⋯N hydrogen-bonding inter­action between one pyridine group of the ligand and an azide N atom of an adjacent complex unit gives a one-dimensional chain structure parallel to the c axis. International Union of Crystallography 2011-06-11 /pmc/articles/PMC3152144/ /pubmed/21836869 http://dx.doi.org/10.1107/S1600536811021234 Text en © Rowthu et al. 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Rowthu, Sankara Rao
Shin, Jong Won
Kim, Seung-Hui
Kim, Jong Jin
Min, Kil Sik
Diazido­{(S)-1-phenyl-N,N-bis­[(2-pyrid­yl)meth­yl]ethanamine}­copper(II)
title Diazido­{(S)-1-phenyl-N,N-bis­[(2-pyrid­yl)meth­yl]ethanamine}­copper(II)
title_full Diazido­{(S)-1-phenyl-N,N-bis­[(2-pyrid­yl)meth­yl]ethanamine}­copper(II)
title_fullStr Diazido­{(S)-1-phenyl-N,N-bis­[(2-pyrid­yl)meth­yl]ethanamine}­copper(II)
title_full_unstemmed Diazido­{(S)-1-phenyl-N,N-bis­[(2-pyrid­yl)meth­yl]ethanamine}­copper(II)
title_short Diazido­{(S)-1-phenyl-N,N-bis­[(2-pyrid­yl)meth­yl]ethanamine}­copper(II)
title_sort diazido­{(s)-1-phenyl-n,n-bis­[(2-pyrid­yl)meth­yl]ethanamine}­copper(ii)
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3152144/
https://www.ncbi.nlm.nih.gov/pubmed/21836869
http://dx.doi.org/10.1107/S1600536811021234
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