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Propane-1,2-diaminium bis(pyridine-2,6-dicarboxylato-κ(3) O (2),N,O (6))cuprate(II) tetrahydrate
In the title compound, (C(3)H(12)N(2))[Cu(C(7)H(3)NO(4))(2)]·4H(2)O, the Cu(II) atom is six-coordinated in a distorted octahedral geometry by two tridentate pyridine-2,6-dicarboxylate (pydc) ligands. In the crystal, intermolecular O—H⋯O, N—H⋯O and weak C—H⋯O hydrogen bonds, as well as π–π stackin...
| Autores principales: | , , , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
International Union of Crystallography
2011
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| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3152145/ https://www.ncbi.nlm.nih.gov/pubmed/21836964 http://dx.doi.org/10.1107/S1600536811024378 |
| _version_ | 1782209737521102848 |
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| author | Aghabozorg, Hossein Agah, Ali Akbar Notash, Behrouz Mirzaei, Masoud |
| author_facet | Aghabozorg, Hossein Agah, Ali Akbar Notash, Behrouz Mirzaei, Masoud |
| author_sort | Aghabozorg, Hossein |
| collection | PubMed |
| description | In the title compound, (C(3)H(12)N(2))[Cu(C(7)H(3)NO(4))(2)]·4H(2)O, the Cu(II) atom is six-coordinated in a distorted octahedral geometry by two tridentate pyridine-2,6-dicarboxylate (pydc) ligands. In the crystal, intermolecular O—H⋯O, N—H⋯O and weak C—H⋯O hydrogen bonds, as well as π–π stacking interactions between the pyridine rings of the pydc ligands [centroid–centroid distance = 3.4714 (14) Å] are present. C=O⋯π interactions between the carbonyl groups and pyridine rings [O⋯centroid distances = 3.150 (2) and 3.2233 (19) Å] are also observed. |
| format | Online Article Text |
| id | pubmed-3152145 |
| institution | National Center for Biotechnology Information |
| language | English |
| publishDate | 2011 |
| publisher | International Union of Crystallography |
| record_format | MEDLINE/PubMed |
| spelling | pubmed-31521452011-08-11 Propane-1,2-diaminium bis(pyridine-2,6-dicarboxylato-κ(3) O (2),N,O (6))cuprate(II) tetrahydrate Aghabozorg, Hossein Agah, Ali Akbar Notash, Behrouz Mirzaei, Masoud Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title compound, (C(3)H(12)N(2))[Cu(C(7)H(3)NO(4))(2)]·4H(2)O, the Cu(II) atom is six-coordinated in a distorted octahedral geometry by two tridentate pyridine-2,6-dicarboxylate (pydc) ligands. In the crystal, intermolecular O—H⋯O, N—H⋯O and weak C—H⋯O hydrogen bonds, as well as π–π stacking interactions between the pyridine rings of the pydc ligands [centroid–centroid distance = 3.4714 (14) Å] are present. C=O⋯π interactions between the carbonyl groups and pyridine rings [O⋯centroid distances = 3.150 (2) and 3.2233 (19) Å] are also observed. International Union of Crystallography 2011-06-30 /pmc/articles/PMC3152145/ /pubmed/21836964 http://dx.doi.org/10.1107/S1600536811024378 Text en © Aghabozorg et al. 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
| spellingShingle | Metal-Organic Papers Aghabozorg, Hossein Agah, Ali Akbar Notash, Behrouz Mirzaei, Masoud Propane-1,2-diaminium bis(pyridine-2,6-dicarboxylato-κ(3) O (2),N,O (6))cuprate(II) tetrahydrate |
| title | Propane-1,2-diaminium bis(pyridine-2,6-dicarboxylato-κ(3)
O
(2),N,O
(6))cuprate(II) tetrahydrate |
| title_full | Propane-1,2-diaminium bis(pyridine-2,6-dicarboxylato-κ(3)
O
(2),N,O
(6))cuprate(II) tetrahydrate |
| title_fullStr | Propane-1,2-diaminium bis(pyridine-2,6-dicarboxylato-κ(3)
O
(2),N,O
(6))cuprate(II) tetrahydrate |
| title_full_unstemmed | Propane-1,2-diaminium bis(pyridine-2,6-dicarboxylato-κ(3)
O
(2),N,O
(6))cuprate(II) tetrahydrate |
| title_short | Propane-1,2-diaminium bis(pyridine-2,6-dicarboxylato-κ(3)
O
(2),N,O
(6))cuprate(II) tetrahydrate |
| title_sort | propane-1,2-diaminium bis(pyridine-2,6-dicarboxylato-κ(3)
o
(2),n,o
(6))cuprate(ii) tetrahydrate |
| topic | Metal-Organic Papers |
| url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3152145/ https://www.ncbi.nlm.nih.gov/pubmed/21836964 http://dx.doi.org/10.1107/S1600536811024378 |
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