A kinetic study of mercury(II) transport through a membrane assisted by new transport reagent

BACKGROUND: A new organodithiophosphorus derivative, namely O-(1,3-Bispiperidino-2-propyl)-4-methoxy phenyldithiophosphonate, was synthesized and then the kinetic behavior of the transport process as a function of concentration, temperature, stirring rate and solvents was investigated. RESULTS: The...

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Detalles Bibliográficos
Autores principales: Karakus, Mehmet, Alpoguz, Hamza Korkmaz, Kaya, Ahmet, Acar, Nurcan, Görgülü, Ahmet Orhan, Arslan, Mustafa
Formato: Online Artículo Texto
Lenguaje:English
Publicado: BioMed Central 2011
Materias:
Research Article
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3162878/
https://www.ncbi.nlm.nih.gov/pubmed/21762513
http://dx.doi.org/10.1186/1752-153X-5-43
Descripción
Sumario:BACKGROUND: A new organodithiophosphorus derivative, namely O-(1,3-Bispiperidino-2-propyl)-4-methoxy phenyldithiophosphonate, was synthesized and then the kinetic behavior of the transport process as a function of concentration, temperature, stirring rate and solvents was investigated. RESULTS: The compound 1 was characterized by elemental analysis, IR, (1)H and (31)P NMR spectroscopies. The transport of mercury(II) ion by a zwitterionic dithiophosphonate 1 in the liquid membrane was studied and the kinetic behavior of the transport process as a function of concentration, temperature, stirring rate and solvents was investigated. The compound 1 is expected to serve as a model liquid membrane transport with mercury(II) ions. CONCLUSION: A kinetic study of mercury(II) transport through a membrane assisted by O-(1,3-Bispiperidino-2-propyl)-4-methoxy phenyldithiophosphonate was performed. It can be concluded that the compound 1 can be provided a general and straightforward route to remove toxic metals ions such as mercury(II) ion from water or other solution.

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