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Oxidative Coupling as a Biomimetic Approach to the Synthesis of Scytonemin
[Image: see text] The first total synthesis of the dimeric alkaloid pigment scytonemin is described. The key transformations in its synthesis from 3-indole acetic acid are a Heck carbocyclization and a Suzuki–Miyaura cross-coupling, orchestrated in a stereospecific tandem fashion, followed by a bios...
| Autores principales: | , , , , , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
American Chemical Society
2011
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| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3164230/ https://www.ncbi.nlm.nih.gov/pubmed/21786790 http://dx.doi.org/10.1021/ol201812n |