Development of biomimetic catalytic oxidation methods and non-salt methods using transition metal-based acid and base ambiphilic catalysts

This review focuses on the development of ruthenium and flavin catalysts for environmentally benign oxidation reactions based on mimicking the functions of cytochrome P-450 and flavoenzymes, and low valent transition-metal catalysts that replace conventional acids and bases. Several new concepts and...

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Autor principal: MURAHASHI, Shun-Ichi
Formato: Online Artículo Texto
Lenguaje:English
Publicado: The Japan Academy 2011
Materias:
Review
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3165902/
https://www.ncbi.nlm.nih.gov/pubmed/21558760
http://dx.doi.org/10.2183/pjab.87.242
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author MURAHASHI, Shun-Ichi
author_facet MURAHASHI, Shun-Ichi
author_sort MURAHASHI, Shun-Ichi
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description This review focuses on the development of ruthenium and flavin catalysts for environmentally benign oxidation reactions based on mimicking the functions of cytochrome P-450 and flavoenzymes, and low valent transition-metal catalysts that replace conventional acids and bases. Several new concepts and new types of catalytic reactions based on these concepts are described.
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spelling pubmed-31659022012-03-13 Development of biomimetic catalytic oxidation methods and non-salt methods using transition metal-based acid and base ambiphilic catalysts MURAHASHI, Shun-Ichi Proc Jpn Acad Ser B Phys Biol Sci Review This review focuses on the development of ruthenium and flavin catalysts for environmentally benign oxidation reactions based on mimicking the functions of cytochrome P-450 and flavoenzymes, and low valent transition-metal catalysts that replace conventional acids and bases. Several new concepts and new types of catalytic reactions based on these concepts are described. The Japan Academy 2011-05-11 /pmc/articles/PMC3165902/ /pubmed/21558760 http://dx.doi.org/10.2183/pjab.87.242 Text en © 2011 The Japan Academy This is an open access article distributed under the terms of the Creative Commons Attribution License, which permits unrestricted use, distribution, and reproduction in any medium, provided the original work is properly cited.
spellingShingle Review
MURAHASHI, Shun-Ichi
Development of biomimetic catalytic oxidation methods and non-salt methods using transition metal-based acid and base ambiphilic catalysts
title Development of biomimetic catalytic oxidation methods and non-salt methods using transition metal-based acid and base ambiphilic catalysts
title_full Development of biomimetic catalytic oxidation methods and non-salt methods using transition metal-based acid and base ambiphilic catalysts
title_fullStr Development of biomimetic catalytic oxidation methods and non-salt methods using transition metal-based acid and base ambiphilic catalysts
title_full_unstemmed Development of biomimetic catalytic oxidation methods and non-salt methods using transition metal-based acid and base ambiphilic catalysts
title_short Development of biomimetic catalytic oxidation methods and non-salt methods using transition metal-based acid and base ambiphilic catalysts
title_sort development of biomimetic catalytic oxidation methods and non-salt methods using transition metal-based acid and base ambiphilic catalysts
topic Review
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3165902/
https://www.ncbi.nlm.nih.gov/pubmed/21558760
http://dx.doi.org/10.2183/pjab.87.242
work_keys_str_mv AT murahashishunichi developmentofbiomimeticcatalyticoxidationmethodsandnonsaltmethodsusingtransitionmetalbasedacidandbaseambiphiliccatalysts

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