Microphotochemistry: 4,4'-Dimethoxybenzophenone mediated photodecarboxylation reactions involving phthalimides

A series of 4,4'-dimethoxybenzophenone mediated intra- and intermolecular photodecarboxylation reactions involving phthalimides have been examined under microflow conditions. Conversion rates, isolated yields and chemoselectivities were compared to analogous reactions in a batch photoreactor. I...

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Autores principales: Shvydkiv, Oksana, Nolan, Kieran, Oelgemöller, Michael
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Beilstein-Institut 2011
Materias:
Full Research Paper
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3170193/
https://www.ncbi.nlm.nih.gov/pubmed/21915208
http://dx.doi.org/10.3762/bjoc.7.121
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author Shvydkiv, Oksana
Nolan, Kieran
Oelgemöller, Michael
author_facet Shvydkiv, Oksana
Nolan, Kieran
Oelgemöller, Michael
author_sort Shvydkiv, Oksana
collection PubMed
description A series of 4,4'-dimethoxybenzophenone mediated intra- and intermolecular photodecarboxylation reactions involving phthalimides have been examined under microflow conditions. Conversion rates, isolated yields and chemoselectivities were compared to analogous reactions in a batch photoreactor. In all cases investigated, the microreactions gave superior results thus proving the superiority of microphotochemistry over conventional technologies.
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spelling pubmed-31701932011-09-13 Microphotochemistry: 4,4'-Dimethoxybenzophenone mediated photodecarboxylation reactions involving phthalimides Shvydkiv, Oksana Nolan, Kieran Oelgemöller, Michael Beilstein J Org Chem Full Research Paper A series of 4,4'-dimethoxybenzophenone mediated intra- and intermolecular photodecarboxylation reactions involving phthalimides have been examined under microflow conditions. Conversion rates, isolated yields and chemoselectivities were compared to analogous reactions in a batch photoreactor. In all cases investigated, the microreactions gave superior results thus proving the superiority of microphotochemistry over conventional technologies. Beilstein-Institut 2011-08-02 /pmc/articles/PMC3170193/ /pubmed/21915208 http://dx.doi.org/10.3762/bjoc.7.121 Text en Copyright © 2011, Shvydkiv et al. https://creativecommons.org/licenses/by/2.0https://www.beilstein-journals.org/bjoc/termsThis is an Open Access article under the terms of the Creative Commons Attribution License (https://creativecommons.org/licenses/by/2.0), which permits unrestricted use, distribution, and reproduction in any medium, provided the original work is properly cited. The license is subject to the Beilstein Journal of Organic Chemistry terms and conditions: (https://www.beilstein-journals.org/bjoc/terms)
spellingShingle Full Research Paper
Shvydkiv, Oksana
Nolan, Kieran
Oelgemöller, Michael
Microphotochemistry: 4,4'-Dimethoxybenzophenone mediated photodecarboxylation reactions involving phthalimides
title Microphotochemistry: 4,4'-Dimethoxybenzophenone mediated photodecarboxylation reactions involving phthalimides
title_full Microphotochemistry: 4,4'-Dimethoxybenzophenone mediated photodecarboxylation reactions involving phthalimides
title_fullStr Microphotochemistry: 4,4'-Dimethoxybenzophenone mediated photodecarboxylation reactions involving phthalimides
title_full_unstemmed Microphotochemistry: 4,4'-Dimethoxybenzophenone mediated photodecarboxylation reactions involving phthalimides
title_short Microphotochemistry: 4,4'-Dimethoxybenzophenone mediated photodecarboxylation reactions involving phthalimides
title_sort microphotochemistry: 4,4'-dimethoxybenzophenone mediated photodecarboxylation reactions involving phthalimides
topic Full Research Paper
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3170193/
https://www.ncbi.nlm.nih.gov/pubmed/21915208
http://dx.doi.org/10.3762/bjoc.7.121
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AT oelgemollermichael microphotochemistry44dimethoxybenzophenonemediatedphotodecarboxylationreactionsinvolvingphthalimides

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